Rhodium-mediated formation of peroxides from dioxygen: Isolation of hydroperoxo, silylperoxo, and methylperoxo intermediates

被引：64

作者：

Ahijado, M

Braun, T

Noveski, D

Kocher, N

Neumann, B

Stalke, D

Stammler, HG

机构：

[1] Univ Bielefeld, Fak Chem, D-33501 Bielefeld, Germany

[2] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 42期

关键词：

fluorinated ligands; oxygenation; peroxides; peroxo complexes; rhodium;

D O I：

10.1002/anie.200501615

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Out of thin air, a rhodium complex converts molecular oxygen into hydrogen peroxide, bis(trimethylsilyl) peroxide, and methyl hydroperoxide. Intermediate η1-hydroperoxo and η1-silylperoxo, and η1-methylperoxo complexes have been isolated. Another η1-methylperoxo (see picture) and an η1- hydroperoxo complex have been characterized by X-ray crystallography. (Chemical Equation Presented) © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

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收藏

页码：6947 / 6951

页数：5

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