Calixarene-Based Nanoscale Coordination Cages

被引：213

作者：

Liu, Mei ^{[1
,3
]}

Liao, Wuping ^{[1
]}

Hu, Chunhua ^{[2
]}

Du, Shangchao ^{[1
,3
]}

Zhang, Hongjie ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China

[2] NYU, Dept Chem, New York, NY 10003 USA

[3] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 07期

基金：

中国国家自然科学基金;

关键词：

cage compounds; calixarenes; cobalt; crystal engineering; tripodal ligands; METAL-ORGANIC FRAMEWORKS; RETICULAR SYNTHESIS; SORPTION PROPERTIES; TRANSITION-METAL; MOLECULAR CAGE; POLYHEDRA; LIGAND; CHEMISTRY; CAPSULES; CAVITAND;

D O I：

10.1002/anie.201106732

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecular shuttlecocks: The introduction of tripodal ternary acids (red; see picture) to the cobalt/calixarene (green) systems led to the formation of four unprecedented calixarene-based nanoscale coordination cages through a [6+8] condensation. The overall periphery diameters of the nanocages ranged from 3.3 to 4.7 nm, and there were two sizes for the internal cavities (1.1 and 1.7 nm). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1585 / 1588

页数：4

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