Origin of the Ultra-nonlinear Switching Kinetics in Oxide-Based Resistive Switches

被引:298
作者
Menzel, Stephan [1 ]
Waters, Matthias [2 ]
Marchewka, Astrid [1 ]
Boettger, Ulrich [1 ]
Dittmann, Regina [2 ]
Waser, Rainer [1 ,2 ]
机构
[1] Rhein Westfal TH Aachen, Inst Mat Elect Engn & Informat Technol, D-52074 Aachen, Germany
[2] Forschungszentrum Julich, Peter Grunberg Inst, D-52425 Julich, Germany
关键词
resistive switching; switching kinetics; oxygen vacancies; temperature simulation; nanoelectronics; memristors; STRONTIUM-TITANATE; DEFECT CHEMISTRY; MECHANISM; SRTIO3; TRANSITION; MEMORY; CONDUCTIVITY; COEXISTENCE; RESISTANCE; MODEL;
D O I
10.1002/adfm.201101117
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Experimental pulse lengthpulse voltage studies of SrTiO3 memristive cells are reported, which reveal nonlinearities in the switching kinetics of more than nine orders of magnitude. The results are interpreted using an electrothermal 2D finite element model. The nonlinearity arises from a temperature increase in a few-nanometer-thick disc-shaped region at the Ti electrode and a corresponding exponential increase in oxygen-vacancy mobility. The model fully reproduces the experimental data and it provides essential design rules for optimizing the cell concept of nanoionic resistive memories. The model is generic in nature: it is applicable to all those oxides which become n-conducting upon chemical reduction and which show significant ion conductivity at elevated temperatures.
引用
收藏
页码:4487 / 4492
页数:6
相关论文
共 49 条
[1]  
[Anonymous], 2001, CRC MAT SCI ENG HDB
[2]   Current switching of resistive states in magnetoresistive manganites [J].
Asamitsu, A ;
Tomioka, Y ;
Kuwahara, H ;
Tokura, Y .
NATURE, 1997, 388 (6637) :50-52
[3]   Highly scalable non-volatile resistive memory using simple binary oxide driven by asymmetric unipolar voltage pulses [J].
Baek, IG ;
Lee, MS ;
Seo, S ;
Lee, MJ ;
Seo, DH ;
Suh, DS ;
Park, JC ;
Park, SO ;
Kim, HS ;
Yoo, IK ;
Chung, UI ;
Moon, JT .
IEEE INTERNATIONAL ELECTRON DEVICES MEETING 2004, TECHNICAL DIGEST, 2004, :587-590
[4]   Reproducible switching effect in thin oxide films for memory applications [J].
Beck, A ;
Bednorz, JG ;
Gerber, C ;
Rossel, C ;
Widmer, D .
APPLIED PHYSICS LETTERS, 2000, 77 (01) :139-141
[5]   Occurrence of Both Unipolar Memory and Threshold Resistance Switching in a NiO Film [J].
Chang, S. H. ;
Lee, J. S. ;
Chae, S. C. ;
Lee, S. B. ;
Liu, C. ;
Kahng, B. ;
Kim, D. -W. ;
Noh, T. W. .
PHYSICAL REVIEW LETTERS, 2009, 102 (02)
[6]   Resistive switching mechanism of TiO2 thin films grown by atomic-layer deposition -: art. no. 033715 [J].
Choi, BJ ;
Jeong, DS ;
Kim, SK ;
Rohde, C ;
Choi, S ;
Oh, JH ;
Kim, HJ ;
Hwang, CS ;
Szot, K ;
Waser, R ;
Reichenberg, B ;
Tiedke, S .
JOURNAL OF APPLIED PHYSICS, 2005, 98 (03)
[7]   ELECTRONIC-TRANSPORT BEHAVIOR IN SINGLE-CRYSTALLINE BA0.03SR0.97TIO3 [J].
CHOI, GM ;
TULLER, HL ;
GOLDSCHMIDT, D .
PHYSICAL REVIEW B, 1986, 34 (10) :6972-6979
[8]   MEMRISTIVE DEVICES AND SYSTEMS [J].
CHUA, LO ;
KANG, SM .
PROCEEDINGS OF THE IEEE, 1976, 64 (02) :209-223
[9]   High-temperature heat capacity and thermal expansion of SrTiO3 and SrZrO3 perovskites [J].
deLigny, D ;
Richet, P .
PHYSICAL REVIEW B, 1996, 53 (06) :3013-3022
[10]   ANION DEFICIENCY IN STRONTIUM-TITANATE [J].
FRANCO, MAA ;
REGI, MV .
NATURE, 1977, 270 (5639) :706-707