Efficient synthesis of multifunctional polymers via thiol-epoxy "click" chemistry

被引：184

作者：

De, Swati ^{[1
]}

Khan, Anzar ^{[1
]}

机构：

[1] Swiss Fed Inst Technol, Dept Mat, CH-8093 Zurich, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 25期

关键词：

MACROMOLECULES; FACILE;

D O I：

10.1039/c2cc30434a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We demonstrate high efficiency and simplicity of the thiol-epoxy reaction towards preparation of a wide range of main-chain as well as end-chain multifunctional polymers.

引用

页码：3130 / 3132

页数：3

共 30 条

[1] LiOH-Catalyzed Simple Ring Opening of Epoxides Under Solvent-Free Conditions [J].

Azizi, Najmedin ;

Khajeh-Amiri, Alireza ;

Ghafuri, Hossein ;

Bolourtchian, Mohammad .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2010, 185 (07) :1550-1557

[2] Clicking Pentafluorostyrene Copolymers: Synthesis, Nanoprecipitation, and Glycosylation [J].

Becer, C. Remzi ;

Babiuch, Krzysztof ;

Pilz, David ;

Hornig, Stephanie ;

Heinze, Thomas ;

Gottschaldt, Michael ;

Schubert, Ulrich S. .

MACROMOLECULES, 2009, 42 (07) :2387-2394

[3] Development of thermal and photochemical strategies for thiol-ene click polymer functionalization [J].

Campos, Luis M. ;

Killops, Kato L. ;

Sakai, Ryosuke ;

Paulusse, Jos M. J. ;

Damiron, Denis ;

Drockenmuller, Eric ;

Messmore, Benjamin W. ;

Hawker, Craig J. .

MACROMOLECULES, 2008, 41 (19) :7063-7070

[4] Evaluation and control of thiol-ene/thiol-epoxy hybrid networks [J].

Carioscia, Jacquelyn A. ;

Stansbury, Jeffrey W. ;

Bowman, Christopher N. .

POLYMER, 2007, 48 (06) :1526-1532

[5] Sequential Phosphine-Catalyzed, Nucleophilic Thiol-Ene/Radical-Mediated Thiol-Yne Reactions and the Facile Orthogonal Synthesis of Polyfunctional Materials [J].

Chan, Justin W. ;

Hoyle, Charles E. ;

Lowe, Andrew B. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (16) :5751-+

[6] One-Pot Multistep Reactions Based on Thiolactones: Extending the Realm of Thiol-Ene Chemistry in Polymer Synthesis [J].

Espeel, Pieter ;

Goethals, Fabienne ;

Du Prez, Filip E. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (06) :1678-1681

[7]

FRINGUELLI F, 2004, TARGETS HETEROCYCL S, V8, P146

[8] Macromolecules at surfaces: Research challenges and opportunities from tribology to biology [J].

Granick, S ;

Kumar, SK ;

Amis, EJ ;

Antonietti, M ;

Balazs, AC ;

Chakraborty, AK ;

Grest, GS ;

Hawker, CJ ;

Janmey, P ;

Kramer, EJ ;

Nuzzo, R ;

Russell, TP ;

Safinya, CR .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2003, 41 (22) :2755-2793

[9] Thio-click modification of poly [2-(3-butenyl)-2-oxazoline] [J].

Gress, Anja ;

Volkel, Antje ;

Schlaad, Helmut .

MACROMOLECULES, 2007, 40 (22) :7928-7933

[10] Macromolecular thiolysis of oxiranes: end-group modification of RAFT prepared homopolymers [J].

Harvison, M. Alyse ;

Davis, Thomas P. ;

Lowe, Andrew B. .

POLYMER CHEMISTRY, 2011, 2 (06) :1347-1354

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