Palladium-catalyzed electrochemical carbonylation of 2-amino-1-alkanols to oxazolidin-2-ones under very mild conditions

被引:32
作者
Chiarotto, I [1 ]
Feroci, M [1 ]
机构
[1] Univ Roma La Sapienza, Dipartimento Ingn Chim Mat Mat Prime & Met, I-00161 Rome, Italy
关键词
D O I
10.1016/S0040-4039(01)00497-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new procedure for an efficient synthesis of oxazolidin-2-ones was developed. 2-Amino-1-alkanols undergo oxidative carbonylation under atmospheric pressure of carbon monoxide at room temperature using Pd(II) catalyst in combination with its anodic recycling at a graphite electrode. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3451 / 3453
页数:3
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