A New Strategy to Microporous Polymers: Knitting Rigid Aromatic Building Blocks by External Cross-Linker

被引：570

作者：

Li, Buyi ^{[1
]}

Gong, Ruini ^{[1
]}

Wang, Wei ^{[2
]}

Huang, Xin ^{[1
]}

Zhang, Wang ^{[1
]}

Li, Huanmin ^{[1
]}

Hu, Chunxiao ^{[1
]}

Tan, Bien ^{[1
]}

机构：

[1] Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Wuhan 430074, Peoples R China

[2] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

来源：

MACROMOLECULES | 2011年 / 44卷 / 08期

基金：

中国国家自然科学基金;

关键词：

ULTRAHIGH SURFACE-AREA; ORGANIC FRAMEWORKS; NANOPOROUS POLYMER; HYDROGEN; NETWORKS; CRYSTALLINE; METHANE; STORAGE;

D O I：

10.1021/ma200630s

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A series of microporous polymers has been obtained via a low-cost versatile strategy, which involves "knitting" rigid aromatic building blocks, such as benzene, biphenyl, 1,3,5-triphenylbenzene, methylbenzene, chlorobenzene, and phenol using an external cross-linker. These materials are predominantly microporous and exhibit high surface areas. Moreover, different building blocks can generate materials with different pore structures, functional groups and application properties, which are significant: for materials design.

引用

页码：2410 / 2414

页数：5

共 39 条

[1] Rapid generation and control of microporosity, bimodal pore size distribution, and surface area in Davankov-type hyper-cross-linked resins
Ahn, JH
Jang, JE
Oh, CG
Ihm, SK
Cortez, J
Sherrington, DC
[J]. MACROMOLECULES, 2006, 39 (02) : 627 - 632
[2] Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area
Ben, Teng
Ren, Hao
Ma, Shengqian
Cao, Dapeng
Lan, Jianhui
Jing, Xiaofei
Wang, Wenchuan
Xu, Jun
Deng, Feng
Simmons, Jason M.
Qiu, Shilun
Zhu, Guangshan
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (50) : 9457 - 9460
[3] SOLVENT-ACCESSIBLE SURFACES OF PROTEINS AND NUCLEIC-ACIDS
CONNOLLY, ML
[J]. SCIENCE, 1983, 221 (4612) : 709 - 713
[4] Porous, crystalline, covalent organic frameworks
Côté, AP
Benin, AI
Ockwig, NW
O'Keeffe, M
Matzger, AJ
Yaghi, OM
[J]. SCIENCE, 2005, 310 (5751) : 1166 - 1170
[5] Homochiral Metal-Organic Frameworks for Heterogeneous Asymmetric Catalysis
Dang, Dongbin
Wu, Pengyan
He, Cheng
Xie, Zhong
Duan, Chunying
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (41) : 14321 - 14323
[6] Functionalized Conjugated Microporous Polymers
Dawson, Robert
Laybourn, Andrea
Clowes, Rob
Khimyak, Yaroslav Z.
Adams, Dave J.
Cooper, Andrew I.
[J]. MACROMOLECULES, 2009, 42 (22) : 8809 - 8816
[7] Troger's base-functionalised organic nanoporous polymer for heterogeneous catalysis
Du, Xin
Sun, Yalei
Tan, Bien
Teng, Qingfeng
Yao, Xiaojun
Su, Chengyong
Wang, Wei
[J]. CHEMICAL COMMUNICATIONS, 2010, 46 (06) : 970 - 972
[8] Designed synthesis of 3D covalent organic frameworks
El-Kaderi, Hani M.
Hunt, Joseph R.
Mendoza-Cortes, Jose L.
Cote, Adrien P.
Taylor, Robert E.
O'Keeffe, Michael
Yaghi, Omar M.
[J]. SCIENCE, 2007, 316 (5822) : 268 - 272
[9] A chromium terephthalate-based solid with unusually large pore volumes and surface area
Férey, G
Mellot-Draznieks, C
Serre, C
Millange, F
Dutour, J
Surblé, S
Margiolaki, I
[J]. SCIENCE, 2005, 309 (5743) : 2040 - 2042
[10] Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications
Furukawa, Hiroyasu
Yaghi, Omar M.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (25) : 8875 - 8883

← 1 2 3 4 →