Analysis of coordination and organometallic compounds using photoionisation mass spectrometric techniques

被引:10
作者
Dorcier, A
Dyson, PJ [1 ]
McIndoe, JS
机构
[1] Ecole Polytech Fed Lausanne, Inst Chim Mol & Biol, EPFL, BCH, CH-1015 Lausanne, Switzerland
[2] Univ Victoria, Dept Chem, Victoria, BC V8W 3V6, Canada
关键词
atmospheric chemistry; electrospray ionisation; mass spectrometry; transition metals;
D O I
10.1002/ejic.200300459
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A range of coordination and organometallic compounds have been analysed by quadrupole ion-trap mass spectrometry using various photoionisation methods. Atmospheric-pressure photo ionisation (APPI), which combines atmospheric-pressure chemical ionisation (APCT) with a photolysis lamp, was compared with the new technique photo-assisted electrospray ionisation (PAESI). Additionally, the atmospheric pressure matrix-assisted laser desorption ionisation (AP-MALDI) was also evaluated and compared to MALDI quadrupole ion-trap time-of-flight (MALDI-QIT-TOF) mass spectrometry. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).
引用
收藏
页码:4294 / 4297
页数:4
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