Analysis of organometallic compounds using ion trap mass spectrometry

被引:90
作者
Dyson, PJ [1 ]
McIndoe, JS
机构
[1] Ecole Polytech Fed Lausanne, Inst Chim Mol & Biol, BCH, CH-1015 Lausanne, Switzerland
[2] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
关键词
mass spectrometry; electrospray ionisation; ion trap; organometallic compounds; clusters; ionic clusters;
D O I
10.1016/S0020-1693(03)00369-4
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Ion traps are an increasingly common presence as mass analysers in commercial bench-top mass spectrometers. Such instruments, usually interfaced with electrospray ionisation or nanospray sources, are invariably aimed at organic and biological applications, such as in the analysis of proteins, pharmaceuticals, organics, biomarkers, metabolites, etc. However, the abilities of ion trap mass spectrometers (extraordinary sensitivity, good resolution, MS" for structural information) can be profitably employed in the analysis of inorganic and organometallic compounds. We highlight these abilities, identify various problems and suggest the areas that will perhaps benefit most from employment of ion trap instruments. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:68 / 74
页数:7
相关论文
共 39 条
[1]   [Ru(η6-p-cymene)Cl2(pta)] (pta=1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane):: a water soluble compound that exhibits pH dependent DNA binding providing selectivity for diseased cells [J].
Allardyce, CS ;
Dyson, PJ ;
Ellis, DJ ;
Heath, SL .
CHEMICAL COMMUNICATIONS, 2001, (15) :1396-1397
[2]   Ionic liquids as matrixes for matrix-assisted laser desorption/ionization mass spectrometry [J].
Armstrong, DW ;
Zhang, LK ;
He, LF ;
Gross, ML .
ANALYTICAL CHEMISTRY, 2001, 73 (15) :3679-3686
[3]   Preparation of buta-1,3-diynyl complexes of platinum(II) and their use in the construction of neutral molecular squares:: synthesis, structural and theoretical characterisation of cyclo-{Pt(μ-CCCC)(dppe)}4 and related chemistry [J].
Bruce, MI ;
Costuas, K ;
Halet, JF ;
Hall, BC ;
Low, PJ ;
Nicholson, BK ;
Skelton, BE ;
White, AH .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (03) :383-398
[4]   Fragmentation of transition metal carbonyl cluster anions: Structural insights from mass spectrometry [J].
Butcher, CPG ;
Dyson, PJ ;
Johnson, BFG ;
Khimyak, T ;
McIndoe, JS .
CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (04) :944-950
[5]   On the use of breakdown graphs combined with energy-dependent mass spectrometry to provide a complete picture of fragmentation processes [J].
Butcher, CPG ;
Dyson, PJ ;
Johnson, BFG ;
Langridge-Smith, PRR ;
McIndoe, JS ;
Whyte, C .
RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 2002, 16 (16) :1595-1598
[6]   Electrospray mass spectrometry applied inorganic and organometallic chemistry [J].
Colton, R ;
DAgostino, A ;
Traeger, JC .
MASS SPECTROMETRY REVIEWS, 1995, 14 (02) :79-106
[7]   The effect of pH on the hydrogenation of benzene in an aqueous biphase using a ruthenium catalyst [J].
Daguenet, C ;
Dyson, PJ .
CATALYSIS COMMUNICATIONS, 2003, 4 (04) :153-157
[8]  
DEHOFFMANN E, 2002, MASS SPECTROMETRY PR
[9]   Ionic liquid (molten salt) phase organometallic catalysis [J].
Dupont, J ;
de Souza, RF ;
Suarez, PAZ .
CHEMICAL REVIEWS, 2002, 102 (10) :3667-3691
[10]   Insights into the elimination of HCHO from the clusters [Mn(CO)m(COOMe)]- (Mn = Ru6C, m = 16; Mn = Rh6, m = 15) provided by electrospray mass spectrometry [J].
Dyson, PJ ;
Feeder, N ;
Johnson, BFG ;
McIndoe, JS ;
Langridge-Smith, PRR .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (12) :1813-1815