A magnetically recoverable γ-Fe2O3 nanocatalyst for the synthesis of 2-phenylquinazolines under solvent-free conditions

被引:41
作者
Anand, Narani [1 ]
Reddy, Kannapu Hari Prasad [1 ]
Satyanarayana, Tirumalasetty [2 ]
Rao, Kamaraju Seetha Rama [1 ]
Burri, David Raju [1 ]
机构
[1] Indian Inst Chem Technol, Catalysis Lab, Hyderabad 500607, Andhra Pradesh, India
[2] Osmania Univ, PG Coll, Dept Chem, Mirzapur 502249, India
关键词
NANOPARTICLES; FUNCTIONALIZATION; INHIBITORS;
D O I
10.1039/c1cy00341k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A magnetically recoverable iron oxide (gamma-Fe2O3) nanocatalyst (MRIONC) has been synthesized and characterized by XRD, FT-IR, XPS and TEM techniques and it was found that MRIONC is a new and highly efficient green catalyst for the synthesis of 2-phenylquinazolines from 2-aminoarylketones and benzyl amines under solvent free conditions, and in addition MRIONC could be easily recovered by a simple magnetic separation and recycled at least 5 times without significant loss in catalytic activity.
引用
收藏
页码:570 / 574
页数:5
相关论文
共 38 条
[1]   Separable catalysts in one-pot syntheses for greener chemistry [J].
Abu-Reziq, Raed ;
Wang, Dashan ;
Post, Michael ;
Alper, Howard .
CHEMISTRY OF MATERIALS, 2008, 20 (07) :2544-2550
[2]   SYNTHESIS OF 5-SUBSTITUTED QUINAZOLINES AS POTENTIAL ANTIMALARIAL AGENTS [J].
ASHTON, WT ;
HYNES, JB .
JOURNAL OF MEDICINAL CHEMISTRY, 1973, 16 (11) :1233-1237
[3]   Bifunctional Au-Fe3O4 nanopartides for protein separation [J].
Bao, Jie ;
Chen, Wei ;
Liu, Taotao ;
Zhu, Yulin ;
Jin, Peiyuan ;
Wang, Leyu ;
Liu, Junfeng ;
Wei, Yongge ;
Li, Yadong .
ACS NANO, 2007, 1 (04) :293-298
[4]   Synthesis and cytotoxic activity of novel quinazolino-β-carboline-5-one derivatives [J].
Baruah, B ;
Dasu, K ;
Valtilingam, B ;
Mamnoor, P ;
Venkata, PP ;
Rajagopal, S ;
Yeleswarapu, KR .
BIOORGANIC & MEDICINAL CHEMISTRY, 2004, 12 (09) :1991-1994
[5]   Influence of grain size, oxygen stoichiometry, and synthesis conditions on the γ-Fe2O3 vacancies ordering and lattice parameters [J].
Belin, T ;
Guigue-Millot, N ;
Caillot, T ;
Aymes, D ;
Niepce, JC .
JOURNAL OF SOLID STATE CHEMISTRY, 2002, 163 (02) :459-465
[6]   Nucleosides XI.: Synthesis and antiviral evaluation of 5′-alkylthio-5′-deoxy quinazolinone nucleoside derivatives as S-adenosyl-L-homocysteine analogs [J].
Chien, TC ;
Chen, CS ;
Yu, FH ;
Chern, JW .
CHEMICAL & PHARMACEUTICAL BULLETIN, 2004, 52 (12) :1422-1426
[7]   Synthesis of quinazolinones and quinazolines [J].
Connolly, DJ ;
Cusack, D ;
O'Sullivan, TP ;
Guiry, PJ .
TETRAHEDRON, 2005, 61 (43) :10153-10202
[8]  
De Palma R, 2007, J NANOSCI NANOTECHNO, V7, P4626, DOI 10.1166/jnn.2007.002
[9]   In situ XPS analysis of various iron oxide films grown by NO2-assisted molecular-beam epitaxy [J].
Fujii, T ;
de Groot, FMF ;
Sawatzky, GA ;
Voogt, FC ;
Hibma, T ;
Okada, K .
PHYSICAL REVIEW B, 1999, 59 (04) :3195-3202
[10]   Bio-functionalization of monodisperse magnetic nanoparticles and their use as biomolecular labels in a magnetic tunnel junction based sensor [J].
Grancharov, SG ;
Zeng, H ;
Sun, SH ;
Wang, SX ;
O'Brien, S ;
Murray, CB ;
Kirtley, JR ;
Held, GA .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (26) :13030-13035