Carbon dioxide and metal centres: from reactions inspired by nature to reactions in compressed carbon dioxide as solvent

被引：144

作者：

Walther, D ^{[1
]}

Ruben, M ^{[1
]}

Rau, S ^{[1
]}

机构：

[1] Univ Jena, Inst Anorgan & Analyt Chem, D-07743 Jena, Germany

来源：

COORDINATION CHEMISTRY REVIEWS | 1999年 / 182卷

关键词：

CO2; activation; carbamato metal complexes; enzyme models; supercritical CO2; catalysis;

D O I：

10.1016/S0010-8545(98)00200-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Aspects of the chemistry of CO2 at metal centres are reviewed with emphasis on the formation of metal carbamato complexes from CO2 (an essential step in the activation of some enzymes containing carbamato groups as ligands), recent results of photochemical activation reactions of CO2 and catalytic reactions at metal complexes in compressed CO2 acting as reaction medium or as both solvent and substrate. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：67 / 100

页数：34

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