Carbon dioxide and metal centres: from reactions inspired by nature to reactions in compressed carbon dioxide as solvent

被引：144

作者：

Walther, D ^{[1
]}

Ruben, M ^{[1
]}

Rau, S ^{[1
]}

机构：

[1] Univ Jena, Inst Anorgan & Analyt Chem, D-07743 Jena, Germany

来源：

COORDINATION CHEMISTRY REVIEWS | 1999年 / 182卷

关键词：

CO2; activation; carbamato metal complexes; enzyme models; supercritical CO2; catalysis;

D O I：

10.1016/S0010-8545(98)00200-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Aspects of the chemistry of CO2 at metal centres are reviewed with emphasis on the formation of metal carbamato complexes from CO2 (an essential step in the activation of some enzymes containing carbamato groups as ligands), recent results of photochemical activation reactions of CO2 and catalytic reactions at metal complexes in compressed CO2 acting as reaction medium or as both solvent and substrate. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：67 / 100

页数：34

共 192 条

[41] JACK-BEAN UREASE (EC 3.5.1.5) - METALLOENZYME - SIMPLE BIOLOGICAL ROLE FOR NICKEL [J].

DIXON, NE ;

GAZZOLA, C ;

BLAKELEY, RL ;

ZERNER, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (14) :4131-4133

[42]

DOOLEY KM, 1997, IND CHEM RES, V26, P1910

[43]

FISCHER B, 1980, J AM CHEM SOC, V102, P7361

[44] TOWARD PHOTOCHEMICAL CARBON-DIOXIDE ACTIVATION BY TRANSITION-METAL COMPLEXES [J].

FUJITA, E ;

BRUNSCHWIG, BS ;

OGATA, T ;

YANAGIDA, S .

COORDINATION CHEMISTRY REVIEWS, 1994, 132 :195-200

[45] CARBON-DIOXIDE ACTIVATION BY COBALT MACROCYCLES - EVIDENCE OF HYDROGEN-BONDING BETWEEN BOUND CO2 AND THE MACROCYCLE IN SOLUTION [J].

FUJITA, E ;

CREUTZ, C ;

SUTIN, N ;

BRUNSCHWIG, BS .

INORGANIC CHEMISTRY, 1993, 32 (12) :2657-2662

[46] Visible-light induced photofixation of carbon dioxide into aromatic ketones and benzyl halides catalysed by CdS nanocrystallites [J].

Fujiwara, H ;

Kanemoto, M ;

Ankyu, H ;

Murakoshi, K ;

Wada, Y ;

Yanagida, S .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1997, (02) :317-321

[47] Olefin metathesis in compressed carbon dioxide [J].

Furstner, A ;

Koch, D ;

Langemann, K ;

Leitner, W ;

Six, C .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (22) :2466-2469

[48] STRUCTURAL INVESTIGATION OF THE GROUND AND EXCITED-STATES OF CIRE(CO)3(4,4'-BIPYRIDYL)2 USING VIBRATIONAL SPECTROSCOPY [J].

GAMELIN, DR ;

GEORGE, MW ;

GLYN, P ;

GREVELS, FW ;

JOHNSON, FPA ;

KLOTZBUCHER, W ;

MORRISON, SL ;

RUSSELL, G ;

SCHAFFNER, K ;

TURNER, JJ .

INORGANIC CHEMISTRY, 1994, 33 (15) :3246-3250

[49] EXCITED-STATE PROPERTIES AND REACTIVITY OF [RECL(CO)3(2,2'-BIPY)] (2,2'-BIPY = 2,2'-BIPYRIDYL) STUDIED BY TIME-RESOLVED INFRARED-SPECTROSCOPY [J].

GEORGE, MW ;

JOHNSON, FPA ;

WESTWELL, JR ;

HODGES, PM ;

TURNER, JJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (19) :2977-2979

[50] The organometallic chemistry of carbon dioxide [J].

Gibson, DH .

CHEMICAL REVIEWS, 1996, 96 (06) :2063-2095

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