Nanostructured Photocatalysts and Their Applications in the Photocatalytic Transformation of Lignocellulosic Biomass: An Overview

被引:151
作者
Colmenares, Juan Carlos [1 ]
Luque, Rafael [2 ]
Campelo, Juan Manuel [2 ]
Colmenares, Fernando [3 ,4 ]
Karpinski, Zbigniew [1 ]
Romero, Antonio Angel [2 ]
机构
[1] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland
[2] Univ Cordoba, Dept Quim Organ, E-14014 Cordoba, Spain
[3] Cranfield Univ, Sch Engn, Cranfield MK43 0AL, Beds, England
[4] St Bonaventure Univ, Gas Turbine Engn Grp, Fac Engn, Bogota, Colombia
关键词
heterogeneous photocatalysis; nanoparticles; biomass transformation; solar energy; biofuels; DIP-COATING METHOD; RELATIVE PHOTONIC EFFICIENCIES; PHASE SELECTIVE PHOTOOXIDATION; VISIBLE-LIGHT PHOTOCATALYSIS; TUNABLE MESOPOROUS MATERIALS; DOPED TIO2 POWDERS; SOL-GEL PROCESS; HYDROGEN-PRODUCTION; HETEROGENEOUS PHOTOCATALYSIS; TITANIUM-DIOXIDE;
D O I
10.3390/ma2042228
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Heterogeneous photocatalysis offer many possibilities for finding appropiate environmentally friendly solutions for many of the the problems affecting our society (i.e., energy issues). Researchers are still looking for novel routes to prepare solid photocatalysts able to transform solar into chemical energy more efficiently. In many developing countries, biomass is a major energy source, but currently such countries lack of the technology to sustainably obtain chemicals and/or fuels from it. The Roadmap for Biomass Technologies, authored by 26 leading experts from academia, industry, and government agencies, has predicted a gradual shift back to a carbohydrate-based economy. Biomass and biofuels appear to hold the key to satisfy the basic needs of our societies for the sustainable production of liquid fuels and high value-added chemicals without compromising the scenario of future generations. In this review, we aim to discuss various design routes for nanostructured photocatalytic solid materials in view of their applications in the selective transformation of lignocellulosic biomass to high value-added chemicals.
引用
收藏
页码:2228 / 2258
页数:31
相关论文
共 186 条
[21]   Tunable mesoporous materials optimised for aqueous phase esterifications [J].
Budarin, Vitaly L. ;
Clark, James H. ;
Luque, Rafael ;
Macquarrie, Duncan J. ;
Koutinas, Apostolis ;
Webb, Colin .
GREEN CHEMISTRY, 2007, 9 (09) :992-995
[22]   Photoinduced reactivity of titanium dioxide [J].
Carp, O ;
Huisman, CL ;
Reller, A .
PROGRESS IN SOLID STATE CHEMISTRY, 2004, 32 (1-2) :33-177
[23]   Photocatalytically active TiO2 thin films produced by surfactant-assisted sol-gel processing [J].
Cernigoj, U ;
Stangar, UL ;
Trebse, P ;
Krasovec, UO ;
Gross, S .
THIN SOLID FILMS, 2006, 495 (1-2) :327-332
[24]   Characterization and photocatalytic activity of K+-doped TiO2 photocatalysts [J].
Chen, Lung-Chuan ;
Huang, Chao-Ming ;
Tsai, Fu-Ren .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 265 (1-2) :133-140
[25]   Microstructure characterization and photocatalytic activity of mesoporous TiO2 films with ultrafine anatase nanocrystallites [J].
Chen, Yongjun ;
Stathatos, Elias ;
Dionysiou, Dionysios D. .
SURFACE & COATINGS TECHNOLOGY, 2008, 202 (10) :1944-1950
[26]   Sol-gel preparation of mesoporous photocatalytic TiO2 films and TiO2/Al2O3 composite membranes for environmental applications [J].
Choi, H ;
Stathatos, E ;
Dionysiou, DD .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2006, 63 (1-2) :60-67
[27]   EFFECTS OF METAL-ION DOPANTS ON THE PHOTOCATALYTIC REACTIVITY OF QUANTUM-SIZED TIO2 PARTICLES [J].
CHOI, WY ;
TERMIN, A ;
HOFFMANN, MR .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (10) :1091-1092
[28]   Fabrication and photocatalytic characterizations of ordered nanoporous X-doped (X = N, C, S, Ru, Te, and Si) TiO2/Al2O3 films on ITO/glass [J].
Chu, SZ ;
Inoue, S ;
Wada, K ;
Di, L ;
Suzuki, J .
LANGMUIR, 2005, 21 (17) :8035-8041
[29]   Synthesis, characterization and photocatalytic activity of different metal-doped titania systems [J].
Colmenares, J. C. ;
Aramendia, M. A. ;
Marinas, A. ;
Marinas, J. M. ;
Urbano, F. J. .
APPLIED CATALYSIS A-GENERAL, 2006, 306 (120-127) :120-127
[30]   Does interfacial charge transfer compete with charge carrier recombination? A femtosecond diffuse reflectance investigation of TiO2 nanoparticles [J].
Colombo, DP ;
Bowman, RM .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (47) :18445-18449