Electrogenerated conjugated polymers incorporating a ferrocene-derivatized-(3,4-ethylenedioxythiophene)

被引：39

作者：

Brisset, H

Navarro, AE

Moustrou, C

Perepichka, IF

Roncali, J

机构：

[1] Univ Mediterranee, Lab Mat Mol & Biomat, CNRS, UMR 6114, F-13288 Marseille 9, France

[2] Univ Angers, IMMO, Grp Syst Conjugues Lineaires, CNRS,UMR 6501, F-49045 Angers, France

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2004年 / 6卷 / 03期

关键词：

modified electrodes; ethylenedioxythiophene; electropolymerization; ferrocene;

D O I：

10.1016/j.elecom.2003.12.010

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A ferrocene-derivatized ethylenedioxythiophene (EDOT) (1) has been synthesized. The co-electropolymerization of this precursor with hydroxymethyl EDOT (2) and a two-site precusor involving two EDOT groups linked by a polyether chain (3) has been investigated in potentiodynamic and potentiostatic conditions in acetonitrile and nitrobenzene. The analysis of the electrochemical behavior of the films grown under various conditions show that potentiostatic copolymerization of 1 and 3 in nitrobenzene leads to a stable electroactive copolymer which retains the electroactivity of the ferrocene group even in aqueous medium. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：249 / 253

页数：5

共 19 条

[1] Modification of the electrochemical and electronic properties of electrogenerated poly(3,4-ethylenedioxythiophene) by hydroxymethyl and oligo(oxyethylene)substituents [J].