Photomagnetic effects in polycyanometallate compounds: An intriguing future chemically based technology?

被引：136

作者：

Dei, A ^{[1
]}

机构：

[1] Univ Florence, LAMM Dipartimento Chim, ISTM Res Unit, I-50019 Florence, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 08期

关键词：

cyanides; electron transfer; magnetic properties; photochemistry; single-molecule magnets;

D O I：

10.1002/anie.200461413

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Out of the blue: Photoinduced magnetism in polymeric "Prussian Blue" analogues is a well understood phenomenon that can even occur near room temperature. The lessons learned are now being transferred to the synthesis of molecular cyanide-bridged single-molecule magnets (see picture; Mo yellow, C black, N blue, Cu purple) whose magnetic properties change drastically on light irradiation. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1160 / 1163

页数：4

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