Water-soluble and stable dinitrogen phosphine complexes trans-[ReCl(N2)(PTA-H)n(PTA)4-n]n+ (n=0-4), the first with 1,3,5-triaza-7-phosphaadamantane

被引：30

作者：

Smolenski, Piotr ^{[1
]}

Pombeiro, Armando J. L. ^{[1
]}

机构：

[1] Univ Tecn Lisboa, Ctr Quim Estrutural, Inst Super Tecn, P-1049001 Lisbon, Portugal

来源：

DALTON TRANSACTIONS | 2008年 / 01期

关键词：

D O I：

10.1039/b712360d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first dinitrogen complexes with the hydrosoluble PTA ligand, or its protonated form PTA-H, trans-[ReCl(N-2)(PTA-H) n(PTA)(4-n)](n+) (n = 0-4), are prepared, shown to be soluble and stable in water, interconvertible by stepwise protonation/deprotonation and to form, upon N-2 loss, the corresponding penta-coordinate compounds. Dinitrogen displacement by CO affords trans-[ReCl(CO)(PTA)(4)].

引用

页码：87 / 91

页数：5

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