A carbon monoxide PROX reactor for PEM fuel cell automotive application

被引:102
作者
Dudfield, CD [1 ]
Chen, R [1 ]
Adcock, PL [1 ]
机构
[1] Loughborough Univ Technol, Dept Automot & Aeronaut Engn, Loughborough LE11 3TU, Leics, England
关键词
carbon monoxide oxidation; methanol steam reforming; fuel cells;
D O I
10.1016/S0360-3199(00)00131-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Loughborough University have designed, constructed and evaluated a compact CO preferential oxidation (PROX) reactor for PEM fuel cell applications. The reactor design is based upon the catalyst coating of high surface area heat transfer technology. Catalyst screening studies have revealed a mixed transition metal oxide promoted platinum-ruthenium formulation to be suitable for the particular reactor application i.e. acceptable CO oxidation activity and selectivity within a temperature range of 130-200 degreesC. The CO PROX reactor design has been sized for 20 kW, PEM fuel cell applications, and is based upon 2 x 2 1 catalyst washcoated compact fin heat exchangers. The PROX reactor has being successfully integrated and commissioned with a methanol steam reformer with reductions in fuel CO concentrations of 2.7% to < 20 ppm being subsequently demonstrated. (C) 2001 International Association for Hydrogen Energy. Published by Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:763 / 775
页数:13
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