Preparative biotransformations

被引：94

作者：

Roberts, SM ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1999年 / 01期

关键词：

D O I：

10.1039/a806595k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This review of the 1997 literature features enzyme-catalysed reactions that are of real and potential importance to synthetic organic chemistry. Biotransformations involving some well-known hydrolases are discussed as well as less-popular catalysts that are being increasingly used in the synthesis of complex carbohydrates. The use of oxidoreductases, mono-oxygenases, dioxygenases and carbon-carbon bond-forming enzymes in preparative chemistry is summarized. The increased interest in the employment of polypeptides and catalytic antibodies in synthesis is described.

引用

页码：1 / +

页数：22

共 325 条

[81] Enzymes in organic chemistry .5. First and chemo-enzymatic synthesis of alpha-aminooxyphosphonic acids of high enantiomeric excess
Drescher, M
Hammerschmidt, F
[J]. TETRAHEDRON, 1997, 53 (13) : 4627 - 4636
[82] Synthetic applications of polymeric alpha-amino acids
Ebrahim, S
Wills, M
[J]. TETRAHEDRON-ASYMMETRY, 1997, 8 (19) : 3163 - 3173
[83] Enzyme-catalyzed reactions .28. Synthesis of the adrenergic bronchodilators (R)-terbutaline and (R)-salbutamol from (R)-cyanohydrins
Effenberger, F
Jager, J
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (12) : 3867 - 3873
[84] Stereoselective synthesis of (S)-3,4-methylenedioxyamphetamines from (R)-cyanohydrins
Effenberger, F
Jager, J
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (08) : 1370 - 1374
[85] Preparation of (S)-naproxen by enantioselective hydrolysis of racemic naproxen amide with resting cells of Rhodococcus erythropolis MP50 in organic solvents
Effenberger, F
Graef, BW
Osswald, S
[J]. TETRAHEDRON-ASYMMETRY, 1997, 8 (16) : 2749 - 2755
[86] Preparation of (S)-piperazine-2-carboxylic acid, (R)-piperazine-2-carboxylic acid, and (S)-piperidine-2-carboxylic acid by kinetic resolution of the corresponding racemic carboxamides with stereoselective amidases in whole bacterial cells
Eichhorn, E
Roduit, JP
Shaw, N
Heinzmann, K
Kiener, A
[J]. TETRAHEDRON-ASYMMETRY, 1997, 8 (15) : 2533 - 2536
[87] Regio- and stereoselectivity of particulate methane monooxygenase from Methylococcus capsulatus (Bath)
Elliott, SJ
Zhu, M
Tso, L
Nguyen, HHT
Yip, JHK
Chan, SI
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (42) : 9949 - 9955
[88] Asymmetric epoxidation of chalcones with chirally modified lithium and magnesium tert-butyl peroxides
Elston, CL
Jackson, RFW
MacDonald, SJF
Murray, PJ
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (04): : 410 - 412
[89] Chemoenzymatic and electrochemical oxidations in the synthesis of octahydroisoquinolines for conversion to morphine. Relative merits of radical vs. acid-catalyzed cyclizations.
Endoma, MA
Butora, G
Claeboe, CD
Hudlicky, T
Abboud, KA
[J]. TETRAHEDRON LETTERS, 1997, 38 (51) : 8833 - 8836
[90] Enantiopure purpurosamine C type glycosyl donors - An improved access from rac-acrolein dimer - Biocatalytic resolution
Erbeck, S
Prinzbach, H
[J]. TETRAHEDRON LETTERS, 1997, 38 (15) : 2653 - 2656

← 4 5 6 7 8 9 10 11 12 13 →