Epoxidized soy bean oil (ESBO) migrating from the gaskets of lids into food packed in glass jars

被引:34
作者
Fankhauser-Noti, A
Fiselier, K
Biedermann, S
Biedermann, M
Grob, K [1 ]
Armellini, F
Rieger, K
Skjevrak, I
机构
[1] Official Food Control Author Canton Zurich, CH-8030 Zurich, Switzerland
[2] Inst Food Invest State Vorarlberg, A-6901 Bregenz, Austria
[3] Norwegian Food Safety Author, N-4325 Sandnes, Norway
关键词
epoxidized soy bean oil (ESBO); on-line LC-GC; gaskets; lids for glass jars; infant food; oily food;
D O I
10.1007/s00217-005-1194-4
中图分类号
TS2 [食品工业];
学科分类号
0832 ;
摘要
Epoxidized soy bean oil (ESBO) was determined in foods packed in glass jars closed by lids with a poly(vinyl chloride) (PVC) gasket. The methyl ester of a diepoxy linoleic acid isomer was measured, using transesterification directly in the homogenized food and on-line HPLC-GC-FID analysis. Infant foods from the Swiss market consisting of vegetables, potato and rice or muesli with fruits and berries contained less than 7 mg/kg ESBO, but meat (its fat?) strongly increased ESBO migration up to 86 mg/kg. Some 12% of the products exceeded 15 mg/kg. Austrian and Norwegian samples gave similar results. Edible oil strongly extracts the ESBO from the gasket in food contact within a few weeks. Since this part of the gasket on average contained 91 mg ESBO, the legal limit is likely to be far exceeded whenever the food contains free oil contacting the gasket, such as oily sauces or vegetables and fish in oil. In fact, the mean ESBO concentration in 86 samples was 166 mg/kg, with a maximum of 580 mg/kg.
引用
收藏
页码:416 / 422
页数:7
相关论文
共 19 条
[11]   European survey of contamination of homogenized baby food by epoxidized soybean oil migration from plasticized PVC gaskets [J].
Fantoni, L ;
Simoneau, C .
FOOD ADDITIVES AND CONTAMINANTS, 2003, 20 (11) :1087-1096
[12]  
Hammarling L, 1998, FOOD ADDIT CONTAM A, V15, P203
[13]  
Ministry of Agriculture Fisheries and Food (MAFF), 1999, FOOD SURV INF SHEET
[14]  
PICCININI P, 2004, 3 INT S FOOD PACK IL
[15]  
*SCI COMM FOOD, 1999, COMP EV SCF CERT MON
[16]  
*SCI COMM FOOD, 2002, OP SCF INT FAT CONS
[17]   STUDIES ON THE STABILIZATION OF POLYVINYL-CHLORIDE) WITH EPOXIDES - TRANSFORMATION PRODUCTS AND THEIR MIGRATION FROM PACKAGING TO FOODS [J].
SHEPHERD, MJ ;
GILBERT, J .
EUROPEAN POLYMER JOURNAL, 1981, 17 (03) :285-289
[18]   GAS CHROMATOGRAPHY-MASS SPECTROMETRY OF A SERIES OF FATTY-ACID METHYL-ESTER CHLOROHYDRINS AND THEIR TRIMETHYLSILYL DERIVATIVES [J].
STARTIN, JR ;
GILBERT, J ;
MCWEENY, DJ .
JOURNAL OF CHROMATOGRAPHY, 1978, 152 (02) :495-499
[19]   Determination of fat content and fatty acid composition through 1-min transesterification in the food sample principles [J].
Suter, B ;
Grob, K ;
Pacciarelli, B .
ZEITSCHRIFT FUR LEBENSMITTEL-UNTERSUCHUNG UND-FORSCHUNG A-FOOD RESEARCH AND TECHNOLOGY, 1997, 204 (04) :252-258