Modular self-assembled multiporphyrin cages with tunable shape

被引：33

作者：

Alessio, Enzo ^{[1
]}

Casanova, Massimo ^{[1
]}

Zangrando, Ennio ^{[1
]}

Iengo, Elisabetta ^{[1
]}

机构：

[1] Univ Trieste, Dept Chem & Pharmaceut Sci, Trieste, Italy

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 42期

关键词：

ORGANOMETALLIC BOXES; METALLACYCLES; COORDINATION;

D O I：

10.1039/c2cc31420g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three new molecular cages-a trigonal prism (2) and two cubic-shaped boxes of increasing size (3, 4)-featuring as many as 10 porphyrins were obtained in quantitative yields by self-assembly of a single bis-zincporphyrin metallacycle (1) with appropriate polytopic N-linkers: the trigonal planar tpt or the cruciform porphyrins 4'-TPyP and 4'-TPhPyP.

引用

页码：5112 / 5114

页数：3

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