Tin(IV) bis(perfluoroalkanesulfonyl)amide complex as a highly selective Lewis acid catalyst for Baeyer-Villiger oxidation using hydrogen peroxide in a fluorous recyclable phase

被引：40

作者：

Hao, XH ^{[1
]}

Yamazaki, O ^{[1
]}

Yoshida, A ^{[1
]}

Nishikido, J ^{[1
]}

机构：

[1] Noguchi Inst, Itabashi Ku, Tokyo 1730003, Japan

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 27期

关键词：

Baeyer-Villiger oxidation; biphasic catalysis; hydrogen peroxide; perfluorinated ligand; tin;

D O I：

10.1016/S0040-4039(03)01185-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Sn[N(SO2C8F17)(2)](4) catalyst was shown to give an excellent yield and selectivity in a fluorous biphasic catalytic system for Baeyer-Villiger oxidation of cyclic ketones by 35% aqueous hydrogen peroxide, a green, safe and cheap oxidant. Furthermore, the catalyst was completely recovered and reused in the fluorous immobilized phase without loss of activity. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：4977 / 4980

页数：4

共 29 条

[21] Electrophilic activation of hydrogen peroxide: Selective oxidation reactions in perfluorinated alcohol solvents [J].