One-Pot Synthesis of Core-Expanded Naphthalene Diimides: Enabling N-Substituent Modulation for Diverse n-Type Organic Materials

被引：61

作者：

Hu, Yunbin ^{[1
]}

Qin, Yunke ^{[1
]}

Gao, Xike ^{[1
]}

Zhang, Fengjiao ^{[2
]}

Di, Chong-an ^{[2
]}

Zhao, Zheng ^{[1
]}

Li, Hongxiang ^{[1
]}

Zhu, Daoben ^{[1
,2
]}

机构：

[1] Chinese Acad Sci CAS, Shanghai Inst Organ Chem, Mat Sci Lab, Shanghai 200032, Peoples R China

[2] CAS, Key Lab Organ Solids, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

来源：

ORGANIC LETTERS | 2012年 / 14卷 / 01期

关键词：

THIN-FILM TRANSISTORS; HIGH-ELECTRON-MOBILITY; HIGH-PERFORMANCE; OPTICAL-PROPERTIES; PERYLENE DIIMIDES; MATERIALS DESIGN; SEMICONDUCTORS; DERIVATIVES; CIRCUITS; DYES;

D O I：

10.1021/ol203059r

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A mild and versatile one-pot synthesis of core-expanded naphthalene dilmides has been developed, which undergoes a nucleophilic aromatic substitution reaction and then an imidization reaction, allowing an easy and low-cost access to diverse n-type organic materials. Some newly synthesized compounds by this one-pot operation exhibited high electron mobility of up to 0.70 cm(2) V-1 s(-1) in ambient conditions.

引用

页码：292 / 295

页数：4

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