Surface stress of clean and adsorbate-covered solids

被引:338
作者
Haiss, W [1 ]
机构
[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England
关键词
D O I
10.1088/0034-4885/64/5/201
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Starting with a simple introduction into the phenomenon of surface stress from a thermodynamic as well as from an atomistic viewpoint, the currently available literature on surface stress of clean and adsorbate-covered surfaces is reviewed. The equations which are used to calculate the adsorbate-induced changes of the surface stress tenser from cantilever bending experiments are derived and their limitations are discussed. It is shown for several examples that charge transfer effects have a pronounced influence on the adsorbate-induced surface stress. The linear relation between surface stress and surface charge which has been observed experimentally at the metal-electrolyte interface is rationalized in the framework of thermodynamics. The role of surface stress as a driving force for surface reconstruction and for the structural organization of surfaces on a mesoscopic scale are discussed for a few selected examples. Novel applications of surface stress effects for sensor and actuator applications are described.
引用
收藏
页码:591 / 648
页数:58
相关论文
共 235 条
[1]   INSITU STUDY OF THIN-FILM GROWTH BY INTERNAL-STRESS MEASUREMENT UNDER ULTRAHIGH-VACUUM CONDITIONS - SILVER AND COPPER UNDER THE INFLUENCE OF OXYGEN [J].
ABERMANN, R ;
KOCH, R .
THIN SOLID FILMS, 1986, 142 (01) :65-76
[2]   INTERNAL-STRESS OF VAPOR-DEPOSITED ALUMINUM ON ALUMINUM SUBSTRATE FILMS - EFFECT OF O-2 AND WATER INCORPORATED IN THE SUBSTRATE [J].
ABERMANN, R .
THIN SOLID FILMS, 1990, 188 (02) :385-394
[3]   ELECTRON-MICROSCOPE STRUCTURE AND INTERNAL-STRESS IN THIN SILVER AND GOLD-FILMS DEPOSITED ONTO MGF2 AND SIO SUBSTRATES [J].
ABERMANN, R ;
KOCH, R ;
KRAMER, R .
THIN SOLID FILMS, 1979, 58 (02) :365-370
[4]   SEMIEMPIRICAL CALCULATION OF SOLID-SURFACE TENSIONS IN BODY-CENTERED CUBIC TRANSITION-METALS [J].
ACKLAND, GJ ;
FINNIS, MW .
PHILOSOPHICAL MAGAZINE A-PHYSICS OF CONDENSED MATTER STRUCTURE DEFECTS AND MECHANICAL PROPERTIES, 1986, 54 (02) :301-315
[5]   SPONTANEOUS FORMATION OF STRESS DOMAINS ON CRYSTAL-SURFACES [J].
ALERHAND, OL ;
VANDERBILT, D ;
MEADE, RD ;
JOANNOPOULOS, JD .
PHYSICAL REVIEW LETTERS, 1988, 61 (17) :1973-1976
[6]  
ANDREEV AF, 1981, SOV PHYS JETP, V54, P761
[7]   WRINKLING OF A FREE-SURFACE [J].
ANDREUSSI, F ;
GURTIN, ME .
JOURNAL OF APPLIED PHYSICS, 1977, 48 (09) :3798-3799
[8]  
[Anonymous], [No title captured]
[9]  
[Anonymous], 1958, Z. Kristallogr
[10]   Stress relief in reconstruction [J].
Bach, CE ;
Giesen, M ;
Ibach, H ;
Einstein, TL .
PHYSICAL REVIEW LETTERS, 1997, 78 (22) :4225-4228