CO2 gas sensor with the combination of tetravalent zirconium cation and divalent oxide anion conducting solids with water-insoluble oxycarbonate electrode

被引:17
作者
Imanaka, N [1 ]
Ogura, A [1 ]
Kamikawa, M [1 ]
Adachi, G [1 ]
机构
[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan
基金
日本学术振兴会;
关键词
carbon dioxide; sensor; solid electrolyte; zirconium; oxycarbonate;
D O I
10.1016/S1388-2481(01)00201-6
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Tetravalent Zr4+ ion and divalent O2- ion conductors based on phosphate and oxide, respectively, were applied as components of a CO2 gas sensor with a water-insoluble oxycarbonate auxiliary electrode and a good sensing performance was demonstrated. Since the sensor cell is mainly composed of the components such as Zr4+, P5+ and O2- ions, a considerably high stability was realized from the beginning of its operation, with a rapid response which was reproducible and corresponded to the theoretical values. (C) 2001 Published by Elsevier Science B.V.
引用
收藏
页码:451 / 454
页数:4
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