1,4-Bis(diarylamino)-2,5-bis(4-cyanophenylethenyl)benzenes: Fluorophores Exhibiting Efficient Red and Near-Infrared Emissions in Solid State

被引：168

作者：

Shimizu, Masaki ^{[1
]}

Kaki, Rina ^{[1
]}

Takeda, Youhei ^{[1
]}

Hiyama, Tamejiro ^{[1
]}

Nagai, Naomi ^{[2
]}

Yamagishi, Hideo ^{[2
]}

Furutani, Hiroyuki ^{[3
]}

机构：

[1] Kyoto Univ, Dept Mat Chem, Grad Sch Engn, Nishikyo Ku, Kyoto 6158510, Japan

[2] Res & Dev Grp OLED AOMORI Co Ltd, Otsu, Shiga 5200104, Japan

[3] Kaneka Corp, RD Planning & Adm Dept, Kita Ku, Osaka 5308288, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 17期

基金：

日本科学技术振兴机构;

关键词：

arenes; chromophores; fluorescence; luminescence; materials science; LIGHT-EMITTING-DIODES; CONJUGATED POLYMERS; ORGANIC CHROMOPHORES; FLUORESCENT SENSORS; OPTICAL-PROPERTIES; LUMINESCENCE; DESIGN; DYES; ELECTROLUMINESCENCE; CHEMOSENSORS;

D O I：

10.1002/anie.201108943

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecular fluorophores of type A-π-D-π-A (D=donor, A=acceptor) demonstrate solid-state emission in the red to near-infrared region with high efficiency. The emission color can be tuned through the substituents on the diarylamino and cyanophenyl moieties. The electroluminescence performance of the designed fluorophore confirms its potential as an emitter for use in organic light-emitting devices. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4095 / 4099

页数：5

共 83 条

[61] A near-infrared squaraine dye as a latent ratiometric fluorophore for the detection of aminothiol content in blood plasma [J].

Sreejith, Sivaramapanicker ;

Divya, Kizhumuri P. ;

Ajayaghosh, Ayyappanpillai .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (41) :7883-7887

[62] Detection of zinc ions under aqueous conditions using chirality assisted solid-state fluorescence of a bipyridyl based fluorophore [J].

Sreejith, Sivaramapanicker ;

Divya, Kizhumuri P. ;

Ajayaghosh, Ayyappanpillai .

CHEMICAL COMMUNICATIONS, 2008, (25) :2903-2905

[63] Synthesis and characterization of poly(2,5-bis(N-methyl-N-hexylamino)phenylene vinylene), a conjugated polymer for light-emitting diodes [J].

Stenger-Smith, JD ;

Zarras, P ;

Merwin, LH ;

Shaheen, SE ;

Kippelen, B ;

Peyghambarian, N .

MACROMOLECULES, 1998, 31 (21) :7566-7569

[64] A Near-Infrared Neutral pH Fluorescent Probe for Monitoring Minor pH Changes: Imaging in Living HepG2 and HL-7702 Cells [J].

Tang, Bo ;

Yu, Fabiao ;

Li, Ping ;

Tong, Lili ;

Duan, Xia ;

Xie, Ting ;

Wang, Xu .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (08) :3016-3023

[65] Color tuning in benzo[1,2,5]thiadiazole-based small molecules by amino conjugation/deconjugation: Bright red-light-emitting diodes [J].

Thomas, KRJ ;

Lin, JT ;

Velusamy, M ;

Tao, YT ;

Chuen, CH .

ADVANCED FUNCTIONAL MATERIALS, 2004, 14 (01) :83-90

[66] Chemical sensors based on amplifying fluorescent conjugated polymers [J].

Thomas, Samuel W., III ;

Joly, Guy D. ;

Swager, Timothy M. .

CHEMICAL REVIEWS, 2007, 107 (04) :1339-1386

[67] Bright, color-tunable fluorescent dyes in the visible-near-infrared region [J].

Umezawa, Keitaro ;

Nakamura, Yuki ;

Makino, Hiroshi ;

Citterio, Daniel ;

Suzuki, Koji .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (05) :1550-+

[68] Role of Molecular Packing in Determining Solid-State Optical Properties of π-Conjugated Materials [J].

Varghese, Shinto ;

Das, Suresh .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2011, 2 (08) :863-873

[69] 3-Boryl-2,2′-bithiophene as a versatile core skeleton for full-color highly emissive organic solids [J].

Wakamiya, Atsushi ;

Mori, Kenji ;

Yamaguchi, Shigehiro .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (23) :4273-4276

[70] Materials for fluorescence-based optical chemical sensors [J].

Wolfbeis, OS .

JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (27-28) :2657-2669

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