1,4-Bis(diarylamino)-2,5-bis(4-cyanophenylethenyl)benzenes: Fluorophores Exhibiting Efficient Red and Near-Infrared Emissions in Solid State

被引:168
作者
Shimizu, Masaki [1 ]
Kaki, Rina [1 ]
Takeda, Youhei [1 ]
Hiyama, Tamejiro [1 ]
Nagai, Naomi [2 ]
Yamagishi, Hideo [2 ]
Furutani, Hiroyuki [3 ]
机构
[1] Kyoto Univ, Dept Mat Chem, Grad Sch Engn, Nishikyo Ku, Kyoto 6158510, Japan
[2] Res & Dev Grp OLED AOMORI Co Ltd, Otsu, Shiga 5200104, Japan
[3] Kaneka Corp, RD Planning & Adm Dept, Kita Ku, Osaka 5308288, Japan
基金
日本科学技术振兴机构;
关键词
arenes; chromophores; fluorescence; luminescence; materials science; LIGHT-EMITTING-DIODES; CONJUGATED POLYMERS; ORGANIC CHROMOPHORES; FLUORESCENT SENSORS; OPTICAL-PROPERTIES; LUMINESCENCE; DESIGN; DYES; ELECTROLUMINESCENCE; CHEMOSENSORS;
D O I
10.1002/anie.201108943
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Molecular fluorophores of type A-π-D-π-A (D=donor, A=acceptor) demonstrate solid-state emission in the red to near-infrared region with high efficiency. The emission color can be tuned through the substituents on the diarylamino and cyanophenyl moieties. The electroluminescence performance of the designed fluorophore confirms its potential as an emitter for use in organic light-emitting devices. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:4095 / 4099
页数:5
相关论文
共 83 条
[41]   Near-infrared fluorophores containing benzo[c]heterocycle subunits [J].
Meek, Scott T. ;
Nesterov, Evgueni E. ;
Swager, Timothy M. .
ORGANIC LETTERS, 2008, 10 (14) :2991-2993
[42]   Conjugated oligomers with terminal donor-acceptor substitution [J].
Meier, H .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (17) :2482-2506
[43]  
Meier H., 2005, Angew. Chem., V117, P2536
[44]   The electroluminescence of organic materials [J].
Mitschke, U ;
Bäuerle, P .
JOURNAL OF MATERIALS CHEMISTRY, 2000, 10 (07) :1471-1507
[45]  
Mullen K., 2006, ORGANIC LIGHT EMITTI
[46]   Switching of Polymorph-Dependent ESIPT Luminescence of an Imidazo[1,2-a]pyridine Derivative [J].
Mutai, Toshiki ;
Tomoda, Haruhiko ;
Ohkawa, Tatsuya ;
Yabe, Yuji ;
Araki, Koji .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (49) :9522-9524
[47]   Aromatic Ring-Fused BODIPY-Based Conjugated Polymers Exhibiting Narrow Near-Infrared Emission Bands [J].
Nagai, Atsushi ;
Chujo, Yoshiki .
MACROMOLECULES, 2010, 43 (01) :193-200
[48]   Near-infrared solid-state fluorescent naphthooxazine dyes attached with bulky dibutylamino and perfluoroalkenyloxy groups at 6-and 9-positions [J].
Park, So-Yeon ;
Kubota, Yasuhiro ;
Funabiki, Kazumasa ;
Shiro, Motoo ;
Matsui, Masaki .
TETRAHEDRON LETTERS, 2009, 50 (10) :1131-1135
[49]   Near-Infrared Organic Compounds and Emerging Applications [J].
Qian, Gang ;
Wang, Zhi Yuan .
CHEMISTRY-AN ASIAN JOURNAL, 2010, 5 (05) :1006-1029
[50]   Synthesis and Application of Thiadiazoloquinoxaline-Containing Chromophores as Dopants for Efficient Near-Infrared Organic Light-Emitting Diodes [J].
Qian, Gang ;
Zhong, Ze ;
Luo, Min ;
Yu, Dengbin ;
Zhang, Zhiqiang ;
Ma, Dongge ;
Wang, Zhi Yuan .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (04) :1589-1595