Guest-Responsive Reversible Swelling and Enhanced Fluorescence in a Super-Absorbent, Dynamic Microporous Polymer

被引：95

作者：

Rao, K. Venkata ^{[1
]}

Mohapatra, Sudip ^{[2
]}

Maji, Tapas Kumar ^{[1
,2
]}

George, Subi J. ^{[1
]}

机构：

[1] Jawaharlal Nehru Ctr Adv Sci Res JNCASR, Supramol Chem Lab, New Chem Unit, Bangalore 560064, Karnataka, India

[2] Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 15期

关键词：

dynamic frameworks; host-guest systems; microporous materials; oil spills; swelling; PHOTOINDUCED ELECTRON-TRANSFER; FRAMEWORKS; NETWORKS; OIL; ENCAPSULATION;

D O I：

10.1002/chem.201103750

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A swell idea! The guest-responsive reversible swelling and fluorescence enhancement of a dynamic, microporous polymer network is presented. Guest-induced breathing of hydrophobic pores imparts multi-functional properties, such as super-absorbency, phase-selective swelling of oil from water and encapsulation of C 60 (see figure), to this soft micro-porous organic polymer. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4505 / 4509

页数：5

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