Synthesis and post-polymerization modification of maleimide-containing polymers by 'thiol-ene' click and Diels-Alder chemistries

被引:87
作者
Hall, Daniel J. [1 ]
Van den Berghe, Helene M. [1 ]
Dove, Andrew P. [1 ]
机构
[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
基金
英国工程与自然科学研究理事会;
关键词
maleimide; thiol-ene; click; Diels-Alder; post-polymerization modification; LIVING RADICAL POLYMERIZATION; ONE-POT SYNTHESIS; RAFT-GENERATED POLYMERS; BLOCK-COPOLYMERS; HETEROTELECHELIC POLYMERS; FUNCTIONALIZED POLYMERS; PROTEIN PEGYLATION; GIANT AMPHIPHILES; STAR POLYMERS; CONJUGATION;
D O I
10.1002/pi.3121
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This mini-review provides an introduction to the key work in the area of synthesis and post-polymerization functionalization of maleimide-functional polymers. The versatility and utility of the maleimide group in the efficient functionalization of polymers by both 'thiol-ene' Michael addition and Diels-Alder cycloaddition chemistries are highlighted. (C) 2011 Society of Chemical Industry
引用
收藏
页码:1149 / 1157
页数:9
相关论文
共 69 条
[11]   Preparation of 3-arm star polymers (A3) via Diels-Alder click reaction [J].
Dag, Aydan ;
Durmaz, Hakan ;
Hizal, Gurkan ;
Tunca, Umit .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (01) :302-313
[12]  
Diels O, 1928, LIEBIGS ANN CHEM, V460, P98
[13]   A Diels-Alder/Retro diels-alder strategy to synthesize polymers bearing maleimide side chains [J].
Dispinar, Tugba ;
Sanyal, Rana ;
Sanyal, Amitav .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2007, 45 (20) :4545-4551
[14]   Preparation of block copolymers via diels alder reaction of maleimide- and anthracene-end functionalized polymers [J].
Durmaz, H ;
Colakoclu, B ;
Tunca, U ;
Hizal, G .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (05) :1667-1675
[15]   One-Pot Synthesis of Star-Block Copolymers Using Double Click Reactions [J].
Durmaz, Hakan ;
Dag, Aydan ;
Hizal, Alp ;
Hizal, Gurkan ;
Tunca, Umit .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (21) :7091-7100
[16]   One-pot synthesis of ABC type triblock copolymers via in situ click [3+2] and Diels-Alder [4+2] reactions [J].
Durmaz, Hakan ;
Dag, Aydan ;
Altintas, Ozcan ;
Erdogan, Tuba ;
Hizal, Gurkan ;
Tunca, Umit .
MACROMOLECULES, 2007, 40 (02) :191-198
[17]   Cyclic Homo and Block Copolymers Through Sequential Double Click Reactions [J].
Durmaz, Hakan ;
Dag, Aydan ;
Hizal, Gurkan ;
Tunca, Umit .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2010, 48 (22) :5083-5091
[18]   Multiarm Star Polymers with Peripheral Dendritic PMMA Arms Through Diels-Alder Click Reaction [J].
Durmaz, Hakan ;
Dag, Aydan ;
Onen, Ceyda ;
Gok, Ozgul ;
Sanyal, Amitav ;
Hizal, Gurkan ;
Tunca, Umit .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2010, 48 (21) :4842-4846
[19]   Anthracene-maleimide-based Diels-Alder "click chemistry" as a novel route to graft copolymers [J].
Gacal, B. ;
Durmaz, H. ;
Tasdelen, M. A. ;
Hizal, G. ;
Tunca, U. ;
Yagci, Y. ;
Demirel, A. L. .
MACROMOLECULES, 2006, 39 (16) :5330-5336
[20]   Peptide/protein-polymer conjugates: synthetic strategies and design concepts [J].
Gauthier, Marc A. ;
Klok, Harm-Anton .
CHEMICAL COMMUNICATIONS, 2008, (23) :2591-2611