Heck-type 5-endo-trig cyclization promoted by vinylic fluorines:: synthesis of 5-fluoro-3H-pyrroles

被引：75

作者：

Sakoda, K ^{[1
]}

Mihara, J ^{[1
]}

Ichikawa, J ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 37期

关键词：

D O I：

10.1039/b510039a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A 5-endo-trig alkene insertion proceeds under palladium catalysis via aminopalladium species starting from 3,3-difluoro-allyl ketone O-pentafluorobenzoyloximes, providing a facile access to 5-fluoro-3H-pyrroles.

引用

页码：4684 / 4686

页数：3

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