New chiral N-(N,N-dialkylamino)sulfamoyl-1,2-diamine ligands for highly enantioselective transfer hydrogenation of ketones

被引:61
作者
Sterk, D
Stephan, MS
Mohar, B
机构
[1] Natl Inst Chem, SI-1000 Ljubljana, Slovenia
[2] PhosPhoenix SARL, F-75015 Paris, France
关键词
D O I
10.1016/S0957-4166(02)00659-6
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Chiral Ru(II) and Rh(III) complexes of N-(N,N-dialkylamino)sulfamoyl-1,2-diamine catalyze the transfer hydrogenation of various classes of aromatic ketones with high activity and excellent enantioselectivity. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
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页码:2605 / 2608
页数:4
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