Corrosion-protective performance of nano polyaniline/ferrite dispersed alkyd coatings

被引:53
作者
Alam, Javed [1 ]
Riaz, Ufana [1 ]
Ashraf, S. M. [1 ]
Ahmad, Sharif [1 ]
机构
[1] Jamia Millia Islamia, Dept Chem, Mat Res Lab, New Delhi 110025, India
关键词
polyaniline; ferrite; nanocomposites; anticorrosive; polymers;
D O I
10.1007/s11998-007-9058-4
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The application of nanotechnology in the corrosion protection of metals has recently gained momentum. A polymer nanocomposite coating can effectively combine the benefits of organic polymers, such as elasticity and water resistance, to that of advanced inorganic materials, such as hardness and permeability. Environmental impact can also be improved by utilizing nanostructure particulates in coatings and eliminating the requirement of toxic solvents. Nanocomposites have also proven to be an effective alternative to phosphate-chromate pretreatment of metallic substrate, which is hazardous due to the presence of toxic hexavalent chromium. This article reports some of the preliminary investigations on the corrosion-resistance performance of soya oil alkyd, containing polyaniline/ferrite nanocomposite. The corrosion-protective performance was evaluated in terms of physico-mechanical properties, corrosion rate, and SEM studies. The polyaniline/ferrite nanocomposite coatings were found to show a far superior corrosion-resistance performance compared to that of a pure PANI/alkyd system.
引用
收藏
页码:123 / 128
页数:6
相关论文
共 16 条
[1]   Effect of ferrofluid concentration on electrical and magnetic properties of the Fe3O4/PANI nanocomposites [J].
Alam, Javed ;
Riaz, Ufana ;
Ahmad, Sharif .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2007, 314 (02) :93-99
[2]  
[Anonymous], 2000, HDB NANOSTRUCTURED M
[3]   Polyaniline acrylic coatings for corrosion inhibition: the role played by counter-ions [J].
da Silva, JEP ;
de Torresi, SIC ;
Torresi, RM .
CORROSION SCIENCE, 2005, 47 (03) :811-822
[4]   Oxide/polypyrrole composite films for corrosion protection of iron [J].
Garcia, B ;
Lamzoudi, A ;
Pillier, F ;
Le, HNT ;
Deslouis, C .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (12) :B560-B566
[5]  
Guilemany JM, 2005, J THERM SPRAY TECHN, V14, P405, DOI 10.1361/105996305X59350
[6]  
HEILMAN A, 2003, POLYM FILMS EMBEDDED
[7]   Corrosion protection of carbon steel with thermoplastic coatings and alkyd resins containing polyaniline as conductive polymer [J].
Laco, JII ;
Villota, FC ;
Mestres, FL .
PROGRESS IN ORGANIC COATINGS, 2005, 52 (02) :151-160
[8]   Electroconductive polymer nanoparticles preparation and characterization of PANI and PEDOT nanoparticles [J].
Oh, SG ;
Im, SS .
CURRENT APPLIED PHYSICS, 2002, 2 (04) :273-277
[9]   Corrosion protection of aluminum alloys by double-strand polyaniline [J].
Racicot, R ;
Brown, R ;
Yang, SC .
SYNTHETIC METALS, 1997, 85 (1-3) :1263-1264
[10]  
ROSA VA, 2003, J CHIL CHEM SOC, V48