The synthesis and coordination chemistry of 2,6-bis(pyrazolyl)pyridines and related ligands - Versatile terpyridine analogues

被引：311

作者：

Halcrow, MA ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

来源：

COORDINATION CHEMISTRY REVIEWS | 2005年 / 249卷 / 24期

关键词：

tridentate ligands; synthesis; lanthanide complexes; spin-crossover;

D O I：

10.1016/j.ccr.2005.03.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Derivatives of 2,6-di(pyrazol-1-yl)pyridine and 2,6-di(pyrazol-3-yl)pyridine have been used as ligands for 15 years, and have both advantages and disadvantages in this regard compared to the much more widely investigated terpyridines. A review of the synthesis of these and some related ligand types, and a survey of their complex chemistry, are presented. Highlights of the latter include luminescent lanthanide compounds for biological sensing, and iron complexes showing unusual thermal and photochemical spin-state transitions. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：2880 / 2908

页数：29

共 207 条

[1] FLUXIONAL RHENIUM(I) TRICARBONYL HALIDE-COMPLEXES OF PYRAZOLYLPYRIDINE LIGANDS - A DETAILED NUCLEAR-MAGNETIC-RESONANCE INVESTIGATION [J].

ABEL, EW ;

HYLANDS, KA ;

OLSEN, MD ;

ORRELL, KG ;

OSBORNE, AG ;

SIK, V ;

WARD, GN .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (07) :1079-1090

[2] METAL-COMPLEXES OF 1,10-PHENANTHROLINE DERIVATIVES .15. COMPLEXES OF 2-(3,5-DIMETHYLPYRAZOL-1-YL)-1,10-PHENANTHROLINE [J].

ABUSHAMLEH, AS ;

GOODWIN, HA .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1988, 41 (06) :873-880

[3] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].

ADDISON, AW ;

RAO, TN ;

REEDIJK, J ;

VANRIJN, J ;

VERSCHOOR, GC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07) :1349-1356

[4] STRUCTURE AND DYNAMICS OF 3,5-DI-TERT-BUTYLPYRAZOLE PROBED BY COMBINED X-RAY CRYSTALLOGRAPHY AND N-15 SOLID-STATE NMR [J].

AGUILARPARRILLA, F ;

LIMBACH, HH ;

FOCESFOCES, C ;

CANO, FH ;

JAGEROVIC, N ;

ELGUERO, J .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (07) :1965-1970

[5] OBSERVATION OF A SERIES OF DEGENERATE CYCLIC DOUBLE, TRIPLE, AND QUADRUPLE PROTON TRANSFERS IN SOLID PYRAZOLES [J].

AGUILARPARRILLA, F ;

SCHERER, G ;

LIMBACH, HH ;

FOCESFOCES, MDC ;

CANO, FH ;

SMITH, JAS ;

TOIRON, C ;

ELGUERO, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (24) :9657-9659

[6] THE STRENGTH OF HETEROCYCLIC BASES [J].

ALBERT, A ;

GOLDACRE, R ;

PHILLIPS, J .

JOURNAL OF THE CHEMICAL SOCIETY, 1948, (DEC) :2240-2249

[7] The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].

Allen, FH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388

[8]

Almirante N, 1999, SYNLETT, P299

[9] A general, [1+4] approach to the synthesis of 3(5)-substituted pyrazoles from aldehydes. [J].

Almirante, N ;

Cerri, A ;

Fedrizzi, G ;

Marazzi, G ;

Santagostino, M .

TETRAHEDRON LETTERS, 1998, 39 (20) :3287-3290

[10]

ALOMRAN F, 1994, J CHEM RES, P168

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