Evolution of Hierarchical Hexagonal Stacked Plates of CuS from Liquid-Liquid Interface and its Photocatalytic Application for Oxidative Degradation of Different Dyes under Indoor Lighting

被引：257

作者：

Basu, Mrinmoyee ^{[1
]}

Sinha, Arun Kumar ^{[1
]}

Pradhan, Mukul ^{[1
]}

Sarkar, Sougata ^{[1
]}

Negishi, Yuichi ^{[2
]}

Govind ^{[3
]}

Pal, Tarasankar ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kharagpur 721302, W Bengal, India

[2] Tokyo Univ Sci, Tokyo 162, Japan

[3] Natl Phys Lab, New Delhi 110012, India

来源：

ENVIRONMENTAL SCIENCE & TECHNOLOGY | 2010年 / 44卷 / 16期

关键词：

LARGE-SCALE SYNTHESIS; SULFIDE HOLLOW SPHERES; ASSISTED SYNTHESIS; METHYLENE-BLUE; COPPER; NANOTUBES; NANOPARTICLES; FACILE; TIO2; MICROSPHERES;

D O I：

10.1021/es101323w

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Blue solution of copper(II) acetylacetonate complex, [Cu(acac)(2)] in dichloromethane (DCM) and an aqueous alkaline solution of thioacetamide (TAA) constitute a biphasic system The system in a screw cap test tube under a modified hydrothermal (MHT) reaction condition produces a greenish black solid at the liquid liquid interface It has been characterized that the solid mass is an assembly of hexagonal copper sulfide (CuS) nanoplates representing a hierarchical structure The as-synthesized CuS nanoplates are well characterized by several physical techniques An ethanolic dispersion of CuS presents a high band gap energy (2.2 eV) which assists visible light photocatalytic mineralization of different dye molecules Thus a cleanup measure of dye contaminated water body even under indoor light comes true

引用

页码：6313 / 6318

页数：6

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