trans-Bis(ethanolamine-N,O)bis-(saccharinato-N)copper(II)

被引：31

作者：

Yilmaz, VT ^{[1
]}

Andac, O

Topcu, Y

Harrison, WTA

机构：

[1] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Chem, TR-55139 Kurupelit Samsun, Turkey

[2] Univ Aberdeen, Dept Chem, Aberdeen AB24 3UE, Scotland

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2001年 / 57卷

关键词：

D O I：

10.1107/S0108270100019867

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

In the title complex, [Cu(C7H4NO3S)(2)(C2H7NO)(2)], the Cu-II centre lies on an inversion centre and exhibits octahedral coordination, with the two ethanolamine (Hea) and two saccharinate [sac; anionic 1,2-benzisothiazol-3(2H)-one 1,1-dioxide] ligands in a trans configuration. The bidentate Hea ligands bridge axial and equatorial positions and the sac anions occupy equatorial sites around the distorted octahedral copper(II) centre [Cu-O = 2.3263 (16), Cu-N-Hea = 1.9923 (16) and Cu-N-sac = 2.1776 (16) Angstrom].

引用

页码：271 / 272

页数：2

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