X-Ray structure and solvolytic activity towards phosphate diesters of a zirconium(IV) complex

被引：13

作者：

Stulz, E ^{[1
]}

Leumann, C ^{[1
]}

机构：

[1] Univ Bern, Dept Chem & Biochem, CH-3012 Bern, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 03期

关键词：

D O I：

10.1039/a809101c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The X-ray structure of the complex Zr-IV(acac)(2)(salicylideneaminoethanol) [Zr(acac)(2)(sae)] could be solved, and the reactivity of the complex towards phosphate diester solvolysis was investigated showing substantial rate acceleration over background in benzene-methanol solution (ca. 10(8)) and in aqueous medium (ca. 10(5)).

引用

页码：239 / 240

页数：2

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