Apatite formation on alkaline-treated dense TiO2 coatings deposited using the solution precursor plasma spray process

被引:50
作者
Chen, Dianying [2 ]
Jordan, Eric H. [1 ]
Gell, Maurice [2 ]
Wei, Mei [2 ]
机构
[1] Univ Connecticut, Dept Mech Engn, Storrs, CT 06269 USA
[2] Univ Connecticut, Dept Chem Mat & Biomol Engn, Inst Med Sci, Storrs, CT 06269 USA
关键词
solution precursor plasma spray process; titania coatings; apatite; alkaline treatment; simulated body fluid;
D O I
10.1016/j.actbio.2007.11.008
中图分类号
R318 [生物医学工程];
学科分类号
0831 [生物医学工程];
摘要
A dense titania (TiO2) coating was deposited from an ethanol-based solution containing titanium isopropoxide using the solution precursor plasma spray (SPPS) process. XRD and Raman spectrum analyses confirmed that the coating is exclusively composed of rutile TiO2. SEM micrographs show the as-sprayed coating is dense with a uniform thickness and there are no coarse splat boundaries. The as-sprayed coating was chemically treated in 5 M NaOH solution at 80 degrees C for 48 h. The bioactivity of as-sprayed and alkaline-treated coatings was investigated by immersing the coatings in simulated body fluid (SBF) for 14-28 days, respectively. After 28 days immersion, there is a complete layer of carbon ate-containing apatite formed on the alkaline-treated TiO2 coating surface, but none formed on the as-sprayed coating. Published by Elsevier Ltd. on behalf of Acta Materialia Inc.
引用
收藏
页码:553 / 559
页数:7
相关论文
共 32 条
[1]
EFFECT OF COMPOSITION AND THICKNESS ON CORROSION BEHAVIOR OF TIN AND ZRN THIN-FILMS [J].
BROWN, R ;
ALIAS, MN ;
FONTANA, R .
SURFACE & COATINGS TECHNOLOGY, 1993, 62 (1-3) :467-473
[2]
Effect of different surface finishing and of hydroxyapatite coatings on passive and corrosion current of Ti6Al4V alloy in simulated physiological solution [J].
Cabrini, M ;
Cigada, A ;
Rondelli, G ;
Vicentini, B .
BIOMATERIALS, 1997, 18 (11) :783-787
[3]
CHEN DY, 2007, IN PRESS J AM CER SO
[4]
Formation and characterization of hydroxyapatite coating layer on Ti-based metal implant by electron-beam deposition [J].
Choi, JM ;
Kong, YM ;
Kim, S ;
Kim, HE ;
Kwang, CS ;
Lee, IS .
JOURNAL OF MATERIALS RESEARCH, 1999, 14 (07) :2980-2985
[5]
Highly durable thermal barrier coatings made by the solution precursor plasma spray process [J].
Gell, M ;
Xie, LD ;
Ma, XQ ;
Jordan, EH ;
Padture, NP .
SURFACE & COATINGS TECHNOLOGY, 2004, 177 :97-102
[6]
Biomimetic deposition of apatite coating on surface-modified NiTi alloy [J].
Gu, YW ;
Tay, BY ;
Lim, CS ;
Yong, MS .
BIOMATERIALS, 2005, 26 (34) :6916-6923
[7]
Deposition of composite titania/vanadia thin films by chemical bath deposition [J].
Hoffmann, RC ;
Jeurgens, LPH ;
Wildhack, S ;
Bill, J ;
Aldinger, F .
CHEMISTRY OF MATERIALS, 2004, 16 (22) :4199-4201
[8]
Electrochemical characterization of hydroxyapatite coatings on HNO3 passivated 316L SS for implant applications [J].
Kannan, S ;
Balamurugan, A ;
Rajeswari, S .
ELECTROCHIMICA ACTA, 2005, 50 (10) :2065-2072
[9]
Apatite formation on TiO2 in simulated body fluid [J].
Kasuga, T ;
Kondo, H ;
Nogami, M .
JOURNAL OF CRYSTAL GROWTH, 2002, 235 (1-4) :235-240
[10]
Surface potential change in bioactive titanium metal during the process of apatite formation in simulated body fluid [J].
Kim, HM ;
Himeno, T ;
Kawashita, M ;
Lee, JH ;
Kokubo, T ;
Nakamura, T .
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A, 2003, 67A (04) :1305-1309