[Ni(R2pipdt)2](BF4)2(R2pipdt=1,4-disubstituted-piperazine-3,2-dithione) as useful precursors of mixed-ligand dithiolenes of interest for non-linear optics

被引：67

作者：

Bigoli, F

Chen, CT

Wu, WC

Deplano, P ^{[1
]}

Mercuri, ML

Pellinghelli, MA

Pilia, L

Pintus, G

Serpe, A

Trogu, EF

机构：

[1] Univ Cagliari, Dipartimento Chim Inorgan & Analit, Cittadella Monserrato, I-09042 Cagliari, Italy

[2] CNR, Ctr Studio Strutturist Diffrattometr, Dipartimento Chim Gen & Inorgan, I-43100 Parma, Italy

[3] Acad Sinica, Inst Chem, Taipei 11529, Taiwan

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 21期

关键词：

D O I：

10.1039/b106064n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple method to obtain in high yields mixed-ligand nickel-dithiolene complexes, which show strong negative solvatochromism and negative first molecular hyperpolarizability, and the use of Raman spectroscopy to establish the extent of electronic delocalisation in these complexes, are reported.

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页码：2246 / 2247

页数：2

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