Intramolecular carbocupration reaction of unactivated alkynes bearing a stabilized nucleophile: Application to the synthesis of iridoid monoterpenes.

被引：81

作者：

Bouyssi, D ^{[1
]}

Monteiro, N ^{[1
]}

Balme, G ^{[1
]}

机构：

[1] Univ Lyon 1, CNRS, Lab Chim Organ 1, CPE, F-69622 Villeurbanne, France

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 07期

关键词：

alkynes; cyclization; vinyl copper; Iridoid monoterpenes;

D O I：

10.1016/S0040-4039(98)02630-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The copper-promoted cycloisomerization of unsaturated alkynes bearing a stabilized nucleophile is described, providing a novel synthesis of various iridoid monoterpenes. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：1297 / 1300

页数：4

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