A zirconium methacrylate oxocluster as precursor for the low-temperature synthesis of porous zirconium(IV) dicarboxylates

被引：250

作者：

Guillerm, Vincent ^{[3
]}

Gross, Silvia ^{[1
,2
]}

Serre, Christian ^{[3
]}

Devic, Thomas ^{[3
]}

Bauer, Matthias ^{[4
]}

Ferey, Gerard ^{[3
]}

机构：

[1] Univ Padua, CNR, ISTM, Dipartimento Sci Chim, I-35131 Padua, Italy

[2] Univ Padua, INSTM, UdR Padova, I-35131 Padua, Italy

[3] Univ Versailles St Quentin, CNRS, UMR 8180, Inst Lavoisier, F-78035 Versailles, France

[4] Inst Phys Chem, D-70569 Stuttgart, Germany

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 05期

关键词：

ORGANIC HYBRID POLYMERS; METAL-OXIDE CLUSTERS; BUILDING-BLOCKS; OXO CLUSTERS; COORDINATION POLYMERS; RETICULAR SYNTHESIS; DESIGN; STABILITY;

D O I：

10.1039/b914919h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The exchange of the monocarboxylate ligand of the zirconium methacrylate oxocluster Zr6O4(OH)(4)(OMc)(12) (OMc = CH2 = CH(CH3)COO) with dicarboxylic acids (trans, trans muconic acid and terephthalic acid) leads to porous zirconium dicarboxylates exhibiting the UiO-66 architecture; the mild reaction conditions allow the control of their particle size.

引用

页码：767 / 769

页数：3

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