Ultrasound promoted aminolysis of epoxides in aqueous media:: A rapid procedure with no pH adjustment for additive-free synthesis of β-aminoalcohols

被引：39

作者：

Abaee, M. Saeed ^{[1
]}

Hamidi, Vahid ^{[1
]}

Mojtahedi, Mohammad M. ^{[1
]}

机构：

[1] Chem & Chem Engn Res Ctr Iran, Dept Organ Chem, Tehran, Iran

来源：

ULTRASONICS SONOCHEMISTRY | 2008年 / 15卷 / 05期

关键词：

aminolysis; ultrasound irradiation; beta-aminoalcohols; aqueous media;

D O I：

10.1016/j.ultsonch.2007.12.006

中图分类号：

O42 [声学];

学科分类号：

070206 [声学]; 082403 [水声工程];

摘要：

An efficient and environmentally friendly procedure promoted by ultrasound irradiation is developed for stereoselective ring opening of various epoxides with aromatic and aliphatic amines under aqueous conditions in the presence of no catalyst or additive. Chemoselectivity of the protocol is shown by competition of piperidine and aniline to react with different epoxides resulting in exclusive formation of the respective products of piperidine. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：823 / 827

页数：5

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