The reaction of [60]fullerene with lithium fluorenide: Formation of a novel 1,4-adduct of [60]fullerene

被引:71
作者
Murata, Y
Komatsu, K
Wan, TSM
机构
[1] KYOTO UNIV,INST CHEM RES,KYOTO FU,UJI 611,JAPAN
[2] HONG KONG UNIV SCI & TECHNOL,DEPT CHEM,KOWLOON,HONG KONG
基金
日本学术振兴会;
关键词
D O I
10.1016/0040-4039(96)01552-3
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Reaction of fullerene C-60 in THF with lithium fluorenide afforded 1-fluorenyl-1,2-dihyro[60]fullerene 2 after protonation. When the reaction time was extended to 24 h, an unusual adduct 3 was obtained, which had two fluorenyl groups attached at the 1,4-positions of a six-membered ring of C-60. The structure of 3 was confirmed by comparison of its properties with those of corresponding trimethylene-bridged adduct 5. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码:7061 / 7064
页数:4
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