Nickel-catalyzed carboxylation of organozinc reagent with CO2

被引：180

作者：

Ochiai, Hidenori ^{[1
]}

Jang, Minsul ^{[1
]}

Hirano, Koji ^{[1
]}

Yorimitsu, Hideki ^{[1
]}

Shima, Koichiro ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Nishikyo Ku, Kyoto 6158510, Japan

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 13期

关键词：

D O I：

10.1021/ol800764u

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient nickel catalyst system for the carboxylation of organozinc reagents with CO2 under very mild conditions has been developed. The catalyst system complements the conventional methods and enables the direct, synthesis of various saturated carboxylic acid derivatives from the corresponding alkylzinc reagents and CO2.

引用

页码：2681 / 2683

页数：3

共 22 条

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