Molecular alignment of head-to-tail-type poly(3-hexylthiophene-2,5-diyl) and related polymers and compounds on substrates

被引:56
作者
Yamamoto, T [1 ]
Kokubo, H [1 ]
Morikita, T [1 ]
机构
[1] Tokyo Inst Technol, Chem Resources Lab, Yokohama, Kanagawa 2268503, Japan
关键词
molecular alignment; poly(3-hexylthiophene); pi-conjugated polymer; linear hydrocarbon;
D O I
10.1002/polb.1143
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The results of analysis of the alignment of HT-P3HexTh and related polymers and molecules on various substrates were reported. A chloroform-soluble part of the commercially available HT-P3HexTh was poured into an excess amount of methanol to obtain HT-P3HexTh reprecipitated. A chloroform solution of the polymer or triacotane was cast onto the substrates and dried. X-rays were irradiated from the out-of-plane direction and the X-ray diffraction pattern was measured.
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页码:1713 / 1718
页数:6
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