Reversible chemical storage of halogens in few-layer graphene

被引:71
作者
Gopalakrishnan, K. [1 ]
Subrahmanyam, K. S.
Kumar, Prashant
Govindaraj, A.
Rao, C. N. R.
机构
[1] Int Ctr Mat Sci, Chem & Phys Mat Unit, New Chem Unit, Bangalore 560064, Karnataka, India
来源
RSC ADVANCES | 2012年 / 2卷 / 04期
关键词
CHARGE-TRANSFER; FLUOROGRAPHENE; CHLORINATION; NANOTUBES;
D O I
10.1039/c1ra00403d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Few-layer graphene can be chlorinated up to 56 wt.% by irradiation with UV light in a liquid chlorine medium. The chlorinated sample decomposes on heating or on laser irradiation releasing all the chlorine. Similar results have been obtained with the bromination of few-layer graphene.
引用
收藏
页码:1605 / 1608
页数:4
相关论文
共 20 条
[1]   Self-assembly of C60, SWNTs and few-layer graphene and their binary composites at the organic-aqueous interface [J].
Chaturbedy, Piyush ;
Matte, H. S. S. Ramakrishna ;
Voggu, Rakesh ;
Govindaraj, A. ;
Rao, C. N. R. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2011, 360 (01) :249-255
[2]   Reversible fluorination of graphene: Evidence of a two-dimensional wide bandgap semiconductor [J].
Cheng, S. -H. ;
Zou, K. ;
Okino, F. ;
Gutierrez, H. R. ;
Gupta, A. ;
Shen, N. ;
Eklund, P. C. ;
Sofo, J. O. ;
Zhu, J. .
PHYSICAL REVIEW B, 2010, 81 (20)
[3]   Microwave-Assisted Bromination of Double-Walled Carbon Nanotubes [J].
Colomer, J. -F. ;
Marega, R. ;
Traboulsi, H. ;
Meneghetti, M. ;
Van Tendeloo, G. ;
Bonifazi, D. .
CHEMISTRY OF MATERIALS, 2009, 21 (20) :4747-4749
[4]   Monitoring dopants by Raman scattering in an electrochemically top-gated graphene transistor [J].
Das, A. ;
Pisana, S. ;
Chakraborty, B. ;
Piscanec, S. ;
Saha, S. K. ;
Waghmare, U. V. ;
Novoselov, K. S. ;
Krishnamurthy, H. R. ;
Geim, A. K. ;
Ferrari, A. C. ;
Sood, A. K. .
NATURE NANOTECHNOLOGY, 2008, 3 (04) :210-215
[5]   Control of Graphene's Properties by Reversible Hydrogenation: Evidence for Graphane [J].
Elias, D. C. ;
Nair, R. R. ;
Mohiuddin, T. M. G. ;
Morozov, S. V. ;
Blake, P. ;
Halsall, M. P. ;
Ferrari, A. C. ;
Boukhvalov, D. W. ;
Katsnelson, M. I. ;
Geim, A. K. ;
Novoselov, K. S. .
SCIENCE, 2009, 323 (5914) :610-613
[6]   Plasma-chemical bromination of graphitic materials and its use for subsequent functionalization and grafting of organic molecules [J].
Friedrich, J. F. ;
Wettmarshausen, S. ;
Hanelt, S. ;
Mach, R. ;
Mix, R. ;
Zeynalov, E. B. ;
Meyer-Plath, A. .
CARBON, 2010, 48 (13) :3884-3894
[7]   The rise of graphene [J].
Geim, A. K. ;
Novoselov, K. S. .
NATURE MATERIALS, 2007, 6 (03) :183-191
[8]   Photochemical Chlorination of Graphene [J].
Li, Bo ;
Zhou, Lin ;
Wu, Di ;
Peng, Hailin ;
Yan, Kai ;
Zhou, Yu ;
Liu, Zhongfan .
ACS NANO, 2011, 5 (07) :5957-5961
[9]   Fluorographene: A Two-Dimensional Counterpart of Teflon [J].
Nair, Rahul R. ;
Ren, Wencai ;
Jalil, Rashid ;
Riaz, Ibtsam ;
Kravets, Vasyl G. ;
Britnell, Liam ;
Blake, Peter ;
Schedin, Fredrik ;
Mayorov, Alexander S. ;
Yuan, Shengjun ;
Katsnelson, Mikhail I. ;
Cheng, Hui-Ming ;
Strupinski, Wlodek ;
Bulusheva, Lyubov G. ;
Okotrub, Alexander V. ;
Grigorieva, Irina V. ;
Grigorenko, Alexander N. ;
Novoselov, Kostya S. ;
Geim, Andre K. .
SMALL, 2010, 6 (24) :2877-2884
[10]   XPS STUDY OF THE HALOGENATION OF CARBON-BLACK .2. CHLORINATION [J].
PAPIRER, E ;
LACROIX, R ;
DONNET, JB ;
NANSE, G ;
FIOUX, P .
CARBON, 1995, 33 (01) :63-72