Phospha-palladacycles and N-heterocyclic carbene palladium complexes:: efficient catalysts for CC-coupling reactions

被引：356

作者：

Herrmann, WA ^{[1
]}

Öfele, K ^{[1
]}

Von Preysing, D ^{[1
]}

Schneider, SK ^{[1
]}

机构：

[1] Tech Univ Munich, Inst Anorgan Chem, D-85747 Garching, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 687卷 / 02期

关键词：

carbenes; catalysis; CC-coupling; CN-coupling; palladacycles; palladium; phosphines;

D O I：

10.1016/j.jorganchem.2003.07.028

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Due to the great importance of palladium-catalyzed Heck-type reactions in scientific and industrial chemistry, a lot of publications and reviews have been published during the last years describing this matter under different aspects. This article presents a summary of catalytic applications of palladium complexes with phosphorus ligands containing a metallated sp(3)-carbon centre ("palladacycles") or with N-heterocyclic carbene ligands in C-C and C-N coupling reactions of aryl halides including recent results of mechanistic discussions about their role in the catalytic cycle. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：229 / 248

页数：20

共 190 条

[101] Stereoelectronic effects characterizing nucleophilic carbene ligands bound to the Cp*RuCl (Cp* = η5-C5Me5) moiety:: A structural and thermochemical investigation
Huang, JK
Schanz, HJ
Stevens, ED
Nolan, SP
[J]. ORGANOMETALLICS, 1999, 18 (12) : 2370 - 2375
[102] Olefin metathesis-active ruthenium complexes bearing a nucleophilic carbene ligand
Huang, JK
Stevens, ED
Nolan, SP
Petersen, JL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (12) : 2674 - 2678
[103] CHLOROCARBON ACTIVATION - CATALYTIC CARBONYLATION OF DICHLOROMETHANE AND CHLOROBENZENE
HUSER, M
YOUINOU, MT
OSBORN, JA
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (10): : 1386 - 1388
[104] Jafarpour L, 2001, ADV ORGANOMET CHEM, V46, P181
[105] Development of olefin metathesis catalyst precursors bearing nucleophilic carbene ligands
Jafarpour, L
Nolan, SP
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 617 (01) : 17 - 27
[106] HIGHLY STEREOSPECIFIC PALLADIUM-CATALYZED VINYLATION OF VINYLIC HALIDES UNDER SOLID-LIQUID PHASE-TRANSFER CONDITIONS
JEFFERY, T
[J]. TETRAHEDRON LETTERS, 1985, 26 (22) : 2667 - 2670
[107] HIGHLY DISPERSED PD ON MGO AS CATALYST FOR ACTIVATION OF PHENYL CHLORINE BONDS LEADING TO CARBON CARBON BOND FORMATION
KANEDA, K
HIGUCHI, M
IMANAKA, T
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1990, 63 (03): : L33 - L36
[108] KANNAN R, 1987, J ORG CHEM, V52, P5435
[109] KAUFMANN DE, 1997, SYNLETT, V11, P1091
[110] Heterocyclic carbenes. One-pot synthesis of rhodium and iridium carbene complexes
Kocher, C
Herrmann, WA
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 532 (1-2) : 261 - 265

← 6 7 8 9 10 11 12 13 14 15 →