Phospha-palladacycles and N-heterocyclic carbene palladium complexes:: efficient catalysts for CC-coupling reactions

被引:356
作者
Herrmann, WA [1 ]
Öfele, K [1 ]
Von Preysing, D [1 ]
Schneider, SK [1 ]
机构
[1] Tech Univ Munich, Inst Anorgan Chem, D-85747 Garching, Germany
关键词
carbenes; catalysis; CC-coupling; CN-coupling; palladacycles; palladium; phosphines;
D O I
10.1016/j.jorganchem.2003.07.028
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Due to the great importance of palladium-catalyzed Heck-type reactions in scientific and industrial chemistry, a lot of publications and reviews have been published during the last years describing this matter under different aspects. This article presents a summary of catalytic applications of palladium complexes with phosphorus ligands containing a metallated sp(3)-carbon centre ("palladacycles") or with N-heterocyclic carbene ligands in C-C and C-N coupling reactions of aryl halides including recent results of mechanistic discussions about their role in the catalytic cycle. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:229 / 248
页数:20
相关论文
共 190 条
  • [71] HECK RF, 1996, PALLADIUM REAGENTS O
  • [72] Herrmann W. A., 1996, APPL HOMOGENEOUS CAT, P712
  • [73] MULTIPLE BONDS BETWEEN MAIN-GROUP ELEMENTS AND TRANSITION-METALS .139. NUCLEOPHILIC CYCLOCARBENES AS LIGANDS IN METAL-HALIDES AND METAL-OXIDES
    HERRMANN, WA
    OFELE, K
    ELISON, M
    KUHN, FE
    ROESKY, PW
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 480 (1-2) : C7 - C9
  • [74] Functionalized imidazoline-2-ylidene complexes of rhodium and palladium
    Herrmann, WA
    Goossen, LJ
    Spiegler, M
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 547 (02) : 357 - 366
  • [75] Herrmann WA, 2002, ANGEW CHEM INT EDIT, V41, P1290, DOI 10.1002/1521-3773(20020415)41:8<1290::AID-ANIE1290>3.0.CO
  • [76] 2-Y
  • [77] Palladacycles: Efficient new catalysts for the Heck vinylation of aryl halides
    Herrmann, WA
    Brossmer, C
    Reisinger, CP
    Riermeier, TH
    Ofele, K
    Beller, M
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (08) : 1357 - 1364
  • [78] METAL-COMPLEXES OF N-HETEROCYCLIC CARBENES - A NEW STRUCTURAL PRINCIPLE FOR CATALYSTS IN HOMOGENEOUS CATALYSIS
    HERRMANN, WA
    ELISON, M
    FISCHER, J
    KOCHER, C
    ARTUS, GRJ
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (21): : 2371 - 2374
  • [79] N-heterocyclic carbenes
    Herrmann, WA
    Kocher, C
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (20) : 2162 - 2187
  • [80] COMPLEXES AND MECHANISMS OF METAL-CATALYZED C-C COUPLING REACTIONS .2. OXIDATIVE ADDITION OF CHLOROAROMATICS TO PD-0 COMPLEXES - SYNTHESIS, STRUCTURE AND STABILITY OF ARYLPALLADIUM(II) CHLORIDES OF THE PHOSPHORANE SERIES
    HERRMANN, WA
    BROSSMER, C
    PRIERMEIER, T
    OFELE, K
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 481 (01) : 97 - 108