Radical fragmentation of cyclobutanes: An approach to medium ring fused carbocycles

被引:32
作者
Crimmins, MT
Huang, SJ
GuiseZawacki, LE
机构
[1] Venable and Kenan Laboratories of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill
关键词
medium ring carbocycles; 2+2] photocycloadditions; radical fragmentation homoenolate;
D O I
10.1016/0040-4039(96)01433-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The combination of a zinc-copper mediated conjugate addition-cyclization, an intramolecular [2+2] photocycloaddition, and a radical fragmentation reaction provides access to a variety of medium ring fused carbocyclic systems in good overall yields. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码:6519 / 6522
页数:4
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