Homochiral oligopeptides generated via an asymmetric induction in racemic 2D crystallites at the air-water interface;: the system ethyl/thio-ethyl esters of long-chain amphiphilic α-amino acids

被引：8

作者：

Rubinstein, I

Kjaer, K

Weissbuch, I ^{[1
]}

Lahav, M

机构：

[1] Weizmann Inst Sci, Dept Mat & Interfaces, IL-76100 Rehovot, Israel

[2] Riso Natl Lab, Dept Mat Res, DK-4000 Roskilde, Denmark

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 43期

关键词：

D O I：

10.1039/b507457f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

N(epsilon)-stearoyl-lysine-ethyl-ester (C(18)-OE-Lys) operates as an efficient desymmetrizing agent for the generation of homochiral oligopeptides via a reaction catalyzed by silver ions in two-dimensional (2D) quasi-racemic crystallites of the corresponding thio-ester (C(18)-TE-Lys) self-assembled on water.

引用

页码：5432 / 5434

页数：3

共 15 条

[11] Oligopeptides with homochiral sequences generated from racemic precursors that spontaneously separate into enantiomorphous two-dimensional crystalline domains on water surface [J].