Tandem dienyne cross-metathesis/ring-closing metathesis

被引：41

作者：

Smulik, JA ^{[1
]}

Diver, ST ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 02期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(00)01922-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tandem enyne cross-metathesis/ring-closing metathesis between terminal alkynes and 1,5-hexadiene has been demonstrated using the 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene-substituted ruthenium benzylidene complex. Synthesis of 2-substituted 1,3-cyclohexadienes using this one step tandem reaction is reported. In addition, metathesis products were subjected to [4+2] cycloaddition with N-methylmaleimide yielding the corresponding cycloadducts in one synthetic step. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：171 / 174

页数：4

共 27 条

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