Organically templated inorganic/organic hybrid materials:: Synthesis and structures of (C4H12N2)[FeII4(C2O4)3(HPO4)2] and (C5H14N2)[FeIII2(C2O4) (HPO4)3]

被引：72

作者：

Lin, HM

Lii, KH ^{[1
]}

Jiang, YC

Wang, SL

机构：

[1] Acad Sinica, Inst Chem, Taipei 115, Taiwan

[2] Natl Cent Univ, Dept Chem, Chungli 320, Taiwan

[3] Natl Tsing Hua Univ, Dept Chem, Hsinchu 300, Taiwan

来源：

CHEMISTRY OF MATERIALS | 1999年 / 11卷 / 03期

关键词：

D O I：

10.1021/cm980548t

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrothermal treatment of FeCl2. 4H(2)O (or FeCl3. 6H(2)O) and piperazine (or 2-methylpiperazine) with H3PO4 and H2C2O4 in H2O yields two organically templated compounds. The 3-D frameworks are constructed from Fe-II-O (or Fe-III-O) polyhedra and two different ligands, phosphate and oxalate, both coordinated to the iron atoms. The structure of the Fe-III compound is shown.

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页码：519 / +

页数：4

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