Group 12 and heavier Group 13 alkali metal 'ate complexes

被引：67

作者：

Linton, DJ ^{[1
]}

Schooler, P ^{[1
]}

Wheatley, AEH ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

COORDINATION CHEMISTRY REVIEWS | 2001年 / 223卷

关键词：

alkali metal; 'ate complex; Group; 12; 13; solid-state structure;

D O I：

10.1016/S0010-8545(01)00379-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Heterobimetallic complexes in which a Group I metal centre counteracts the negative charge placed on a Group 12 or higher Group 13 metal have been known for some years. Their usefulness in chemical transformations is discussed in the context of the regiospecificity with which they effect reaction and the manner in which it differs to that resulting from the use of homometallic alkali metal reagents. Their structural properties are reported both in solution and in the solid state. Theoretical studies are presented where appropriate. (C) 2001 Elsevier Science B.V. All rights reserved.

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页码：53 / 115

页数：63

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